Answer:
[CO] = 0.078M
[Cl2] = 0.078M
[COCl2] = 0.477M
Explanation:
Based on the reaction:
CO(g) Cl2(g) ⇄ COCl2(g)
<em>Where equilibrium constant, kc, is:</em>
kc = 77.5 = [COCl2] / [CO] [Cl2]
[] represents the equilibrium concentration of each gas. The initial concentration of each gas is:
[CO] = 0.555mol/1.00L = 0.555M
[Cl2] = 0.555M
And equilibrium concentrations are:
[CO] = 0.555M - x
[Cl2] = 0.555M - x
[COCl2] = x
<em>Where x is reaction coordinate</em>
Replacing in kc expression:
77.5 = [x] / [0.555M - x] [0.555M - x]
77.5 = x / 0.308025 - 1.11 x + x²
23.8719 - 86.025 x + 77.5 x² = x
23.8719 - 87.025 x + 77.5 x² = 0
x = 0.477M. Right answer
x = 0.646M. False answer. Produce negative concentrations
Replacing:
<h3>[CO] = 0.555M - 0.477M = 0.078M</h3><h3>[Cl2] = 0.078M</h3><h3>[COCl2] = 0.477M</h3>
And those concentrations are the equilibrium concentrations
Answer:
B
Explanation:
volume occupied by fixed amount of gas is directly proportional to its absolute temperature.
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