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NikAS [45]
3 years ago
10

You are going to standardize your sodium hydroxide by titrating with potassium hydrogen phthalate. As an example, you dissolve 0

.3365 g of potassium hydrogen phthalate, otherwise known as KHP (KHC8H4O4) in water in a 250.0 mL Erlenmeyer flask and then add phenolphthalein indicator. You then titrate with your sodium hydroxide solution, which is in a buret, and you determine that the equivalence point is at 12.44 mL of your sodium hydroxide solution. Determine the molarity of your sodium hydroxide solution. What color will the solution of potassium hydrogen phthalate turn to determine when the equivalence point has been reached
Chemistry
1 answer:
Kay [80]3 years ago
4 0

Answer:

0.13 M

Explanation:

The reaction equation is;

NaOH(aq) + KHC8H4O4(aq) ------> KNaC8H4O4(aq) + H2O(l)

Molar mass of KHP = 204.22 g/mol

Amount of KHP= mass/ molar mass = 0.3365 g/204.22 g/mol = 1.65 × 10^-3 moles

n= CV

Where;

C= concentration

V= volume in dm^3

n= number of moles

C= n/V = 1.65 × 10^-3 moles × 1000/250 = 6.6 × 10^-3 M

If 1 mole of KHP reacts with 1 mole of NaOH

1.65 × 10^-3 moles of KHP will react with 1.65 × 10^-3 moles of NaOH

From

n= CV

We have that only 12.44 ml of NaOH reacted

C= n/V = 1.65 × 10^-3 moles × 1000/12.44

C= 0.13 M

At the equivalence point, the KHP solution turned light pink.

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<u>Answer:</u> The volume of the vessel is 0.1542m^3 and total internal energy is 162.0 kJ.

<u>Explanation:</u>

  • To calculate the volume of water, we use the equation given by ideal gas, which is:

PV=nRT

or,

PV=\frac{m}{M}RT

where,

P = pressure of container = 700 kPa

V = volume of container = ? L

m = Given mass of R-134a = 3.98 kg = 3980 g    (Conversion factor: 1kg = 1000 g)

M = Molar mass of R-134a = 102.03 g/mol

R = Gas constant = 8.31\text{L kPa }mol^{-1}K^{-1}

T = temperature of container = 60^oC=[60+273]K=333K

Putting values in above equation, we get:

700kPa\times V=\frac{3980g}{102.03g/mol}\times 8.31\text{L kPa }\times 333K\\\\V=154.21L

Converting this value into m^3, we use the conversion factor:

1m^3=1000L

So, \Rightarrow (\frac{1m^3}{1000L})\times 154.21L

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U=\frac{3}{2}nRT

or,

U=\frac{3}{2}\frac{m}{M}RT

where,

U = total internal energy

m = given mass of R-134a = 3.98 kg = 3980 g  (Conversion factor: 1kg = 1000g)

M = molar mass of R-134a = 102.03 g/mol

R = Gas constant = 8.314J/K.mol

T = temperature = 60^oC=[60+273]K=333K

Putting values in above equation, we get:

U=\frac{3}{2}\times \frac{3980g}{102.03g/mol}\times 8.314J/K.mol\times 333K\\\\U=161994.6J

Converting this into kilo joules, we use the conversion factor:

1 kJ = 1000 J

So, 161994.6 J = 162.0 kJ

Hence, the volume of the vessel is 0.1542m^3 and total internal energy is 162.0 kJ.

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