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kirza4 [7]
3 years ago
12

Consider the reaction. At equilibrium, the concentrations are as follows. [NOCl] = 1.4 ´ 10–2 M [NO] = 1.2 ´ 10–3 M [Cl2] = 2.2

´ 10–3 M What is the value of Keq for the reaction expressed in scientific notation?
Chemistry
2 answers:
Licemer1 [7]3 years ago
7 0

Answer: For the given chemical reaction, value of k_{eq} is 1.616\times 10^{-5}

Explanation: The chemical reaction according to the question is:

2NOCl\rightarrow 2NO+Cl_2

Equilibrium constant, k_{eq} for the following reaction is given by:

k_{eq}=\frac{[NO]^2[Cl_2]}{[NOCl]^2}

Given:

[NO]=1.2\times 10^{-3}M

[Cl_2]=2.2\times 10^{-3}M

[NOCl]=1.4\times 10^{-2}M

Putting values in above equation we get:

k_{eq}=\frac{(1.2\times 10^{-3})^2(2.2\times 10^{-3})}{(1.4\times 10^{-2})^2}

k_{eq}=1.616\times 10^{-5}

EastWind [94]3 years ago
6 0
2NOCl ⇄ 2NO + Cl₂

K = [NO]²[Cl₂]/[NOCl]
K = [0,0012]²[0,0022]/[0,014]²
K = 0,000000003/0,000196
K = 0,000016163
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Answer:

Explanation:

The changes in properties from metals to non-metals on a periodic table can be measured and determined by the metallicity or electropositivity of elements.

Metallicity is a measure of the tendency of atoms of an element to lose electrons.

a.

Down a periodic group, metallicity increases.

b.

Across a period from left to right electropositivity or metallicity decreases.

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7 0
3 years ago
2.0L of hydrogen gas is mixed with 3.0L of nitrogen gas at STP in a rigid 5.0L vessel. A reaction occurs, producing ammonia gas
IrinaK [193]

Answer:

Moles NH₃: 0.0593

0.104 moles of N₂ remain

Final pressure: 0.163atm

Explanation:

The reaction of nitrogen with hydrogen to produce ammonia is:

N₂ + 3 H₂ → 2 NH₃

Using PV = nRT, moles of N₂ and H₂ are:

N₂: 1atmₓ3.0L / 0.082atmL/molKₓ273K = 0.134 moles of N₂

H₂: 1atmₓ2.0L / 0.082atmL/molKₓ273K = 0.089 moles of H₂

The complete reaction of N₂ requires:

0.134 moles of N₂ × (3 moles H₂ / 1 mole N₂) = <em>0.402 moles H₂</em>

That means limiting reactant is H₂. And moles of NH₃ produced are:

0.089 moles of H₂ × (2 moles NH₃ / 3 mole H₂) = <em>0.0593 moles NH₃</em>

Moles of N₂ remain are:

0.134 moles of N₂ - (0.089 moles of H₂ × (1 moles N₂ / 3 mole H₂)) = <em>0.104 moles of N₂</em>

And final pressure is:

P = nRT / V

P = (0.104mol + 0.0593mol)×0.082atmL/molK×273K / 5.0L

<em>P = 0.163atm</em>

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3 years ago
I need help on both a and b of question 1
marishachu [46]

Answer:

(a) -0.00017 M/s;

(b) 0.00034 M/s

Explanation:

(a) Rate of a reaction is defined as change in molarity in a unit time, that is:

r = \frac{\Delta c}{\Delta t}

Given the following reaction:

2 N_2O_5 (g)\rightleftharpoons 4 NO_2 (g) + O_2 (g)

We may write the rate expression in terms of reactants firstly. Since reactants are decreasing in molarity, we're adding a negative sign. Similarly, if we wish to look at the overall reaction rate, we need to divide by stoichiometric coefficients:

r = -\frac{\Delta [N_2O_5]}{2 \Delta t}

Reaction rate is also equal to the rate of formation of products divided by their coefficients:

r = \frac{\Delta [NO_2]}{4 \Delta t} = \frac{\Delta [O_2]}{\Delta t}

Let's find the rate of disappearance of the reactant firstly. This would be found dividing the change in molarity by the change in time:

r_{N_2O_5} = \frac{0.066 M - 0.100 M}{200.00 s - 0.00 s} = -0.00017 M/s

(b) Using the relationship derived previously, we know that:

-\frac{\Delta [N_2O_5]}{2 \Delta t} = \frac{\Delta [NO_2]}{4 \Delta t}

Rate of appearance of nitrogen dioxide is given by:

r_{NO_2} = \frac{\Delta [NO_2]}{\Delta t}

Which is obtained from the equation:

-\frac{\Delta [N_2O_5]}{2 \Delta t} = \frac{\Delta [NO_2]}{4 \Delta t}

If we multiply both sides by 4, that is:

-\frac{4 \Delta [N_2O_5]}{2 \Delta t} = \frac{\Delta [NO_2]}{\Delta t}

This yields:

[tex]r_{NO_2} = \frac{\Delta [NO_2]}{\Delta t} = -2\frac{\Delta [N_2O_5]}{ \Delta t} = -2\cdot (-0.00017 M/s) = 0.00034 M/s[tex]

5 0
3 years ago
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