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WARRIOR [948]
3 years ago
10

Linolenic acid (C18H30O2 - M.W. = 278.42 g/mol) reacts with hydrogen gas according to the equation: C18H30O2 + 3H2 (g) → C18H36O

2 What volume of hydrogen gas, as measured at P = 1.00 atm and T = 273.15 K, is required to react with 10.5 g of linolenic acid in this reaction?
Chemistry
1 answer:
Ludmilka [50]3 years ago
4 0

Answer:

2.53 L is the volume of H₂ needed

Explanation:

The reaction is: C₁₈H₃₀O₂ + 3H₂ → C₁₈H₃₆O₂

By the way we can say, that 1 mol of linolenic acid reacts with 3 moles of oxygen in order to produce, 1 mol of stearic acid.

By stoichiometry, ratio is 1:3

Let's convert the mass of the linolenic acid to moles:

10.5 g . 1 mol / 278.42 g  = 0.0377 moles

We apply a rule of three:

1 mol of linolenic acid needs 3 moles of H₂ to react

Then, 0.0377 moles will react with (0.0377 . 3 )/1 = 0.113 moles of hydrogen

We apply the Ideal Gases Law to find out the volume (condition of measure are STP) → P . V = n . R . T → V = ( n . R .T ) / P

V = (0.113 mol . 0.082 L.atm/mol.K . 273.15K) 1 atm = 2.53 L

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In this problem we assumed that heat given by the hot body is equal to the heat taken by the cold body.

q_1=-q_2

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where,

c_1 = specific heat of iron = 0.499J/g^oC

c_2 = specific heat of water = 4.18J/g^oC

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T_f = final temperature of mixture = ?

T_1 = initial temperature of iron = 78.1^oC

T_2 = initial temperature of water = 25.0^oC

Now put all the given values in the above formula, we get

(39.9g)\times (0.499J/g^oC)\times (T_f-78.1)^oC=-(50.0g)\times 4.18J/g^oC\times (T_f-25.0)^oC

T_f=29.6^oC

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19.8 kg of C₂H₂ is needed

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Answer:

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Ag changed oxidation number from +1 to 0

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