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frosja888 [35]
3 years ago
10

Zinc reacts with hydrochloric acid according to the reaction equation Zn ( s ) + 2 HCl ( aq ) ⟶ ZnCl 2 ( aq ) + H 2 ( g ) How ma

ny milliliters of 6.50 M HCl ( aq ) are required to react with 2.55 g Zn ( s ) ?
Chemistry
1 answer:
Katen [24]3 years ago
3 0

Answer: 12.0 milliliters of 6.50 M HCl ( aq ) are required to react with 2.55 g Zn.

Explanation:

moles =\frac{\text {given mass}}{\text {Molar mass}}

moles of zinc =\frac{2.55g}{65.38g/mol}=0.0390moles

The balanced chemical equation is :

Zn(s)+2HCl(aq)\rightarrow ZnCl_2(aq)+H_2(g)

According to stoichiometry:

1 mole of zinc reacts with = 2 moles of HCl

Thus 0.0390 moles of zinc reacts with = \frac{2}{1}\times 0.0390=0.0780 moles of HCl

To calculate the volume for given molarity, we use the equation:

\text{Molarity of the solution}=\frac{\text{Moles of solute}\times 1000}{\text{Volume of solution in ml}}     .....(1)

Molarity of HCl solution = 6.50 M

Volume of solution = ?

Putting values in equation 1, we get:

6.50M=\frac{0.0780\times 1000}{\text{Volume of solution in ml}}

{\text{Volume of solution in ml}}=12.0ml

Thus 12.0 ml of 6.50 M HCl ( aq ) are required to react with 2.55 g Zn

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(a) The weight percent HNO3 is 63%.

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wt = \frac{mass \, of \, solute}{mass \, of \, solution}=\frac{mass\,HNO_3}{mass \, HNO_3+mass \, H_2O}\\  \\wt=\frac{1.704}{1.704+1} =\frac{1.704}{2.704}= 0.63

(b) Density of HNO3, in lb/ft3

In this calculation, we use the specific gravity of the solution (1.382). We can start with the volume balance:

V_s=V_{HNO3}+V_w\\\\\frac{M_s}{\rho_s}=\frac{M_{HNO3}}{\rho_{HNO3}}+\frac{M_w}{\rho_w}\\\\\frac{M_{HNO3}}{\rho_{HNO3}} = \frac{M_s}{\rho_s}-\frac{M_w}{\rho_w}\\\\\rho_{HNO3}=\frac{M_{HNO3}}{\frac{M_s}{\rho_s}-\frac{M_w}{\rho_w}} \\\\ \rho_{HNO3}=\frac{1.704}{\frac{2.704}{1.382*\rho_w}+\frac{1}{\rho_w}} \\\\ \rho_{HNO3}=\frac{1.704}{2.956/ \rho_w}= 0.576*\rho_w[tex]V_s=V_{HNO3}+V_w\\\\\frac{M_s}{\rho_s}=\frac{M_{HNO3}}{\rho_{HNO3}}+\frac{M_w}{\rho_w}\\\\\frac{M_{HNO3}}{\rho_{HNO3}} = \frac{M_s}{\rho_s}-\frac{M_w}{\rho_w}\\\\\rho_{HNO3}=\frac{M_{HNO3}}{\frac{M_s}{\rho_s}-\frac{M_w}{\rho_w}} \\\\ \rho_{HNO3}=\frac{1.704}{\frac{2.704}{1.382*\rho_w}-\frac{1}{\rho_w}} \\\\ \rho_{HNO3}=\frac{1.704}{0.956/\rho_w}= 1.782*\rho_w

The density of HNO3 is 1.782 times the density of water (Sp Gr of 1.782). If the density of water is 62.4 lbs/ft3,

\rho_{HNO3}= 1.782*\rho_w=1.782*62.4 \, lbs/ft3=111.2\, lbs/ft3

(c) HNO3 molarity (mol HNO3/m3)

If we use the molar mass of HNO3: 63.012 g/mol, we can say that in 1,704 kg (or 1704 g) of HNO3 there are  1704/63.012=27.04 mol HNO3.

When there are 1.704 kg of NHO3 in solution, the total mass of the solution is (1.704+1)=2.704 kg.

If the specific gravity of the solution is 1.382 and the density of water at 20 degC is 998 kg/m3, the volume of the solution is

Vol=\frac{M_{sol}}{\rho_{sol}}=\frac{2.704\, kg}{1.382*998 \, kg/m3} = 0.00196m3

We can now calculate the molarity as

Molarity HNO_3=\frac{MolHNO3}{Vol}=\frac{27.04mol}{0.00196m3}  =13792 \frac{molHNO3}{m3}

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