Answer:
Less
Explanation:
Since [Cu(NH3)4]2+ and [Cu(H2O)6]2+ are Octahedral Complexes the transitions between d-levels explain the majority of the absorbances seen in those chemical compounds. The difference in energy between d-levels is known as ΔOh (ligand-field splitting parameter) and it depends on several factors:
- The nature of the ligand: A spectrochemical series is a list of ligands ordered on ligand strength. With a higher strength the ΔOh will be higher and thus it requires a higher energy light to make the transition.
- The oxidation state of the metal: Higher oxidation states will strength the ΔOh because of the higher electrostatic attraction between the metal and the ligand
A partial spectrochemical series listing of ligands from small Δ to large Δ:
I− < Br− < S2− < Cl− < N3− < F−< NCO− < OH− < C2O42− < H2O < CH3CN < NH3 < NO2− < PPh3 < CN− < CO
Then NH3 makes the ΔOh higher and it requires a higher energy light to make the transition, which means a shorter wavelength.
Explanation:
According to Bohr's postulates, the electron in the present in the lower energy level can absorb energy and exits to higher energy level. Also, when this electron returns back to its orbit, it emits some energy.
Since the hydrogen consists of 1 electron and 1 proton. The lowest energy configuration of the hydrogen is when n =1 or, when the electron is present in the K-shell or the ground state.
The possible transition for the electron given in the question is :
n = 2, 3 and 4
The schematic diagram of the hydrogen atom consisting of these four quantum levels in which the electron can jump (Absorption) and comeback to from these energy levels (emission) .
Balanced equation: 2Fe + 3H2O → Fe2O3 +3H2
Convert g to mols:
285/55.845 = 5.1034 mols
Mole ratio of Iron and Iron (III) Oxide: 2:1
5.1034/2 = 2.5517 mols
Copper (II) Carbonate + Heat yields copper (II) oxide and carbon dioxide
Molecular Equation: CuCo3 + heat > CuO + CO2
