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bogdanovich [222]
2 years ago
12

Determine which of the following pairs of reactants will result in a spontaneous reaction at 25°C. None of the above pairs will

react. Fe3+(aq) + Mg(s) Pb2+(aq) + Au(s) Ag+(aq) + Br⁻(aq) Li+(aq) + Cr(s)
Chemistry
1 answer:
Alla [95]2 years ago
6 0

Answer:

Only Fe^{3+}+Mg gives spontaneous reaction.

Explanation:

A redox reaction will be spontaneous if standard reduction potential (E^{0}) of the reaction is positive. Because it leads to negative standard gibbs free energy change (\Delta G^{0}), which is a thermodynamic condition for spontaneity of a reaction.

E^{0}=E^{0}(reduction)-E^{0}(oxidation)

Where E^{0}(reduction) and E^{0}(oxidation) represents standard reduction potential of reduction half cell and standard reduction potential of oxidation half cell.

(1) Oxidation:         Mg-2e^{-}\rightarrow Mg^{2+} ;  E_{Mg^{2+}\mid Mg}^{0}=-2.38V

Reduction:         Fe^{3+}+3e^{-}\rightarrow Fe ; E_{Fe^{3+}\mid Fe}^{0}=-0.04V

So, E^{0}=E_{Fe^{3+}\mid Fe}^{0}-E_{Mg^{2+}\mid Mg}^{0}=(-0.04+2.38)V=2.34V

Hence this pair will give spontaneous reaction.

(2) Similarly as above, E^{0}=E_{Pb^{2+}\mid Pb}^{0}-E_{Au^{+}\mid Au}^{0}=(-0.13-1.69)V=-1.82 V

Hence this pair will give non-spontaneous reaction.

(3) Similarly as above, E^{0}=E_{Ag^{+}\mid Ag}^{0}-E_{Br_{2}\mid Br^{-}}^{0}=(0.80-1.07)V=-0.27 V

Hence this pair will give non-spontaneous reaction.

(4)  Similarly as above, E^{0}=E_{Li^{+}\mid Li}^{0}-E_{Cr^{3+}\mid Cr}^{0}=(-3.04+0.74)V=-2.30 V

Hence this pair will give non-spontaneous reaction.

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