Answer:
Only
gives spontaneous reaction.
Explanation:
A redox reaction will be spontaneous if standard reduction potential (
) of the reaction is positive. Because it leads to negative standard gibbs free energy change (
), which is a thermodynamic condition for spontaneity of a reaction.

Where
and
represents standard reduction potential of reduction half cell and standard reduction potential of oxidation half cell.
(1) Oxidation:
; 
Reduction:
; 
So, 
Hence this pair will give spontaneous reaction.
(2) Similarly as above, 
Hence this pair will give non-spontaneous reaction.
(3) Similarly as above, 
Hence this pair will give non-spontaneous reaction.
(4) Similarly as above, 
Hence this pair will give non-spontaneous reaction.