Answer:
It is in violation of the Heisenberg Uncertainty Principle. The Bohr Model considers electrons to have both a known radius and orbit, which is impossible according to Heisenberg. ... The Bohr Model does not account for the fact that accelerating electrons do not emit electromagnetic radiation
Answer:

Explanation:
Hello,
In this case, the dissociation of the given weak acid is:

Therefore, the law of mass action for it turns out:
![Ka=\frac{[H^+][A^-]}{[HA]}](https://tex.z-dn.net/?f=Ka%3D%5Cfrac%7B%5BH%5E%2B%5D%5BA%5E-%5D%7D%7B%5BHA%5D%7D)
That in terms of the change
due to the reaction extent is:

Thus, by solving with the quadratic equation or solver, we obtain:

Which clearly matches with the hydrogen concentration in the solution, therefore, the pH is:

Regards.
Answer:
Depending on the
value of
, the cell potential would be:
, using data from this particular question; or- approximately
, using data from the CRC handbooks.
Explanation:
In this galvanic cell, the following two reactions are going on:
- The conversion between
and
ions,
, and - The conversion between
and
ions,
.
Note that the standard reduction potential of
ions to
is higher than that of
ions to
. Alternatively, consider the fact that in the metal activity series, copper is more reactive than silver. Either way, the reaction is this cell will be spontaneous (and will generate a positive EMF) only if
ions are reduced while
is oxidized.
Therefore:
- The reduction reaction at the cathode will be:
. The standard cell potential of this reaction (according to this question) is
. According to the 2012 CRC handbook, that value will be approximately
.
- The oxidation at the anode will be:
. According to this question, this reaction in the opposite direction (
) has an electrode potential of
. When that reaction is inverted, the electrode potential will also be inverted. Therefore,
.
The cell potential is the sum of the electrode potentials at the cathode and at the anode:
.
Using data from the 1985 and 2012 CRC Handbook:
.
Answer:
18,1 mL of a 0,304M HCl solution.
Explanation:
The neutralization reaction of Ba(OH)₂ with HCl is:
2 HCl + Ba(OH)₂ → BaCl₂ + 2 H₂O
The moles of 17,1 mL≡0,0171L of a 0,161M Ba(OH)₂ solution are:
= 2,7531x10⁻³moles of Ba(OH)₂
By the neutralization reaction you can see that 2 moles of HCl reacts with 1 mole of Ba(OH)₂. For a complete reaction of 2,7531x10⁻³moles of Ba(OH)₂ you need:
= 5,5062x10⁻³moles of HCl.
The volume of a 0,304M HCl solution for a complete neutralization is:
= 0,0181L≡18,1mL
I hope it helps!
Answer:
Explanation:
The formula of the reaction:
KClO₂ → KCl + O₂
To assign oxidation numbers, we have to obey some rules:
- Elements in an uncombined state or one whose atoms combine with one another to form molecules have an oxidation number of zero.
- The charge on simple ions signifies their oxidation number.
- The algebraic sum of all the oxidation number of all atoms in a neutral compound is zero. For radicals with charges, their oxidation number is the charge.
The oxidation number of K in KClO₂:
K + (-1) + 2(-2) = 0
K-5 = 0
K = +5
The oxidation number of K in KCl:
K + (-1) = 0
K = +1
The oxidation number Cl in KClO₂ is -1
For Cl in KCl, the oxidation number is -1
For O in KClO₂, the oxidation number is (2 x -2) = -4
For O in O₂, the oxidation number is 0
K moves from an oxidation state of +5 to +1. This is a gain of electrons and K has undergone reduction. We then say K is reduced.
O moves from an oxidation state of -4 to 0. This is a loss of electrons and O has undergone oxidation. We say O is oxidized.