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sertanlavr [38]
3 years ago
5

Iron(III) oxide and hydrogen react to form iron and water, like this: Fe_2O_3(s) + 3H_2(g) rightarrow 2Fe(s) + 3H_2O(g) At a cer

tain temperature, a chemist finds that a 5.4 L reaction vessel containing a mixture of iron(III) oxide, hydrogen, iron, and water at equilibrium has the following composition: Calculate the value of the equilibrium constant K_c for this reaction. Round your answer to 2 significant digits.

Chemistry
1 answer:
Sergeeva-Olga [200]3 years ago
3 0

Complete Question

The complete question is shown on the first uploaded image

Answer:

The equilibrium constant is  K_c= 2.8*10^{-4}

Explanation:

      From  the question we are told that

              The chemical reaction equation is

      Fe_{2} O_{3}_{(s)} + 3H_{2}_{(g)}  -----> 2Fe_{(s)} + 3H_{2} O_{(g)}

The voume of the misture is  V_m = 5.4L  

  The molar mass of  Fe_{2} O_{3}_{(s)} is a constant with value of  M_{Fe_{2} O_{3}_{(s)} } = 160g/mol

    The molar mass of  H_{2}_{(g)}    is a constant with value of  H_2 = 2g/mol

   

    The molar mass of  H_{2}O    is a constant with value of  H_2O = 18g/mol

Generally the number of moles  is mathematically given as

                     No \ of \ moles \ = \frac{mass}{molar\  mass}

    For   Fe_{2} O_{3}_{(s)}

          No \ of\ moles = \frac{3.54}{160}

                                = 0.022125 \ mols

     For  H_{2}

               No \ of\ moles = \frac{3.63}{2}

                                = 1.815 \ mols

       For  H_{2}O

                         No \ of\ moles = \frac{2.13}{18}

                                              = 0.12 \ mols

Generally the concentration of a compound  is mathematicallyrepresented  as

       Concentration  = \frac{No \ of \ moles }{Volume }

      For   Fe_{2} O_{3}_{(s)}

                Concentration[Fe_2 O_3] = \frac{0.222125}{5.4}

                                         = 4.10*10^{-3}M                          

       For  H_{2}

                  Concentration[H_2] = \frac{1.815}{5.4}

                                           = 0.336M

      For  H_{2}O

                Concentration [H_2O] = \frac{0.12}{5.4}

                                                  = 0.022M

  The equilibrium constant  is mathematically represented as

                K_c = \frac{[concentration \ of \ product]}{[concentration \ of \ reactant ]}

  Considering H_2O  \ for \ product

            And      H_2  \ for  \ reactant

At  equilibrium the

                    K_c = \frac{0.022}{0.336}

                          K_c= 2.8*10^{-4}

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<u>Explanation:</u>

To calculate the number of moles, we use the equation given by ideal gas equation:

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P = Pressure of the gaseous mixture = 1.00 atm

V = Volume of the gaseous mixture = 24.62 L

n = number of moles of the gaseous mixture = ?

R = Gas constant = 0.0821\text{ L atm }mol^{-1}K^{-1}

T = Temperature of the gaseous mixture = 300 K

Putting values in above equation, we get:

1.00atm\times 24.62L=n_{mix}\times 0.0821\text{ L atm }mol^{-1}K^{-1}\times 300K\\\\n_{mix}=\frac{1.00\times 24.62}{0.0821\times 300}=0.9996mol

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Putting values in above equation, we get:

\text{Mass percent of hydrogen gas}=\frac{1.136g}{13.22g}\times 100=8.59\%

Hence, the mass percent of nitrogen gas and hydrogen gas is 91.41 % and 8.59 % respectively.

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