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Free_Kalibri [48]
3 years ago
13

A gas at 400 k is placed in a 4.0 l moveable piston. The gas is cooled to 252 k. What is the new volume of the piston?

Chemistry
1 answer:
katrin [286]3 years ago
6 0

Answer:

2.52L

       

Explanation:

Given parameters:

T₁  = 400K

V₁  = 4L

T₂ = 252K

unknown

V₂ = ?

Solution:

To solve this problem, we are going to apply charle's law. The law states that the volume of a fixed mass of gas is directly proportional to temperature provided pressure is constant.

Mathematically,

               \frac{V_{1} }{T_{1} }  = \frac{V_{2} }{T_{2} }

Substitute and solve for V₂

           \frac{4}{400}  = \frac{V_{2} }{252}

        V₂ = 2.52L

         

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Answer:

The pH of 0.1 M BH⁺ClO₄⁻ solution is <u>5.44</u>

Explanation:

Given: The base dissociation constant: K_{b} = 1 × 10⁻⁴, Concentration of salt: BH⁺ClO₄⁻ = 0.1 M

Also, water dissociation constant: K_{w} = 1 × 10⁻¹⁴

<em><u>The acid dissociation constant </u></em>(K_{a})<em><u> for the weak acid (BH⁺) can be calculated by the equation:</u></em>

K_{a}. K_{b} = K_{w}    

\Rightarrow K_{a} = \frac{K_{w}}{K_{b}}

\Rightarrow K_{a} = \frac{1\times 10^{-14}}{1\times 10^{-4}} = 1\times 10^{-10}

<em><u>Now, the acid dissociation reaction for the weak acid (BH⁺) and the initial concentration and concentration at equilibrium is given as:</u></em>

Reaction involved: BH⁺  +  H₂O  ⇌  B  +  H₃O+

Initial:                     0.1 M                    x         x            

Change:                   -x                      +x       +x

Equilibrium:           0.1 - x                    x         x

<u>The acid dissociation constant: </u>K_{a} = \frac{\left [B \right ] \left [H_{3}O^{+}\right ]}{\left [BH^{+} \right ]} = \frac{(x)(x)}{(0.1 - x)} = \frac{x^{2}}{0.1 - x}

\Rightarrow K_{a} = \frac{x^{2}}{0.1 - x}

\Rightarrow 1\times 10^{-10} = \frac{x^{2}}{0.1 - x}

As, x

\Rightarrow 0.1 - x = 0.1

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\Rightarrow x = \sqrt{1\times 10^{-11}} = 3.16 \times 10^{-6}

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Now, pH = - ㏒ [H⁺] = - ㏒ (3.6 × 10⁻⁶ M) = 5.44

<u>Therefore, the pH of 0.1 M BH⁺ClO₄⁻ solution is 5.44</u>

5 0
3 years ago
A sample of hydrogen gas has an initial pressure of 2.86 atm and an initial volume of 8472 mL If the volume of the
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<h3>Answer:</h3>

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<h3>Explanation:</h3>

Concept tested: Gas laws (Boyle's law)

<u>We are given,</u>

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