<span>The solution of ethanol will have the greatest increase in boiling point.
The formula for boiling point elevation is:
ΔTb = Kb · bB
where
ΔTb = boiling point elevation
Kb = ebullioscopic constant for the solvent
bB = molarity of the solution
Since in the solute is nonionic, we don't have to worry about the molecules of the solute breaking up into multiple ions, thereby increasing the effective molarity of the solution. So which ever solvent has the highest ebullioscopic constant, will have the greatest increase in boiling point. This constant can be calculated by the equation:
Kb = RTb^2M/ΔHv
where
R = Ideal gas constant
Tb = boiling point of pure solvent
M = Molar mass of solvent
ΔHv = heat of vaporization per mole of solvent
For our purposes, we can ignore the idea gas constant, and instead look at only the boiling point, molar mass, and heat of vaporization. Then calculate Tb^2M/ΔHv So let's do so:
(Note: Not bothering to be precise in molar mass. If the end result is close, then I'll bother. Otherwise, just using nice round numbers).
Water
Boiling point: 373.15 K
Molar mass: 18 g/mol
heat of vaporization: 40660 J/mol
Tb^2M/ΔHv: 61.64
Ethanol
Boiling point: 351.52 K
Molar mass: 46 g/mol
heat of vaporization: 38600 J/mol
Tb^2M/ΔHv: 147.26
The value of Tb^2M/ΔHv is significantly greater for ethanol than it is for water (by more than 2 to 1), so it will have the greatest increase in boiling point.</span>
Answer:
random internal motion of atoms and molecule
Explanation:
The primary cause of diffusion is the random internal motion of atoms and molecules.
Randomness of atoms and molecules results in diffusion.
- Diffusion is the movement of particles from a region of high concentration to that of lower concentration.
- Substances often tend to spread out over the concentration gradient.
- Therefore, they have this propensity to be randomized.
Answer: 1) endothernic
2) Yes absorbed
Explanation:
Decomposition is a chemical reaction in which one reactant gives two or more than two products. All decomposition reactions are endothermic reactions as energy is absorbed to break the bonds.
Endothermic reactions are defined as the reactions in which energy of the product is greater than the energy of the reactants. The total energy is absorbed in the form of heat and
for the reaction comes out to be positive.
Exothermic reactions are defined as the reactions in which energy of the product is lesser than the energy of the reactants. The total energy is released in the form of heat and
for the reaction comes out to be negative.