When bromobenzene reacts with propene in a heck reaction (in the presence of pd(php3)4 and et3n) , two constitutional isomers ar
e obtained as the products. give the structures of the two products. interactive 3d display mode?
1 answer:
The Heck reaction is a coupling reaction that combines an unsaturated halide with an alkene in the presence of base and palladium catalyst to provide a substituted alkene. It an important reaction as it forms a carbon-carbon bond and allows substitution on sp² hybridized carbons.
In this example, we have bromobenzene reacting with propene and are told that two constitutional isomers are formed. The expected product is the first one shown which has the benzene substitute onto the terminal end of the alkene. The isomer by-product that is formed is substitution onto the central carbon of the propene which leads to a product with a terminal alkene.
In this example, we have bromobenzene reacting with propene and are told that two constitutional isomers are formed. The expected product is the first one shown which has the benzene substitute onto the terminal end of the alkene. The isomer by-product that is formed is substitution onto the central carbon of the propene which leads to a product with a terminal alkene.
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The given formula contains two carbon along with six hydrogen and an oxygen.
The possible isomers from are ethanol and dimethyl ether.
Ehtanol is an alcohol containing a hydroxyl group whereas dimethyl ether is an ether containing an oxygen between two methyl
The structure of two isomers are:
Answer:
sample B contains the larger density
Explanation:
Given;
volume of sample A, V = 300 mL = 0.3 L
Molarity of sample A, C = 1 M
volume of sample B, V = 145 mL = 0.145 L
Molarity of sample B, C = 1.5 M
molecular mass of sodium chloride, Nacl = 23 + 35.5 = 58.5 g/mol
Molarity is given as;
The reacting mass for sample A = 0.3mol x 58.5 g/mol = 17.55 g
The reacting mass for sample B = 0.2175 mol x 58.5 g/mol = 12.72 g
The density of sample A
The density of sample B
Therefore, sample B contains the larger density