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Anna11 [10]
3 years ago
15

A compound with the molecular formula C10H10O4 produces a 1H NMR spectrum that exhibits only two signals, both singlets. One sig

nal appears at 3.9 ppm with a relative integration value of 79. The other signal appears at 8.1 ppm with a relative integration value of 52. Draw the structure of this compound.

Chemistry
1 answer:
Kamila [148]3 years ago
8 0

Answer:

The attached figure shows the structure of dimethyl terephthalate.

Explanation:

Dimethyl terephthalate is a compound whose formula is C6H4 (COOCH3) 2. It is a diester produced from terephthalic acid and methanol. It is characterized by being a white solid. Another method for the preparation is from p-xylene and methanol, which is characterized by having an oxidation and an esterification.

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Answer:

\large \boxed{109.17 \, ^{\circ}\text{C}}

Explanation:

Data:

50/50 ethylene glycol (EG):water

V = 4.70 gal

ρ(EG) = 1.11 g/mL

ρ(water) = 0.988 g/mL

Calculations:

The formula for the boiling point elevation ΔTb is

\Delta T_{b} = iK_{b}b

i is the van’t Hoff factor —  the number of moles of particles you get from 1 mol of solute. For EG, i = 1.

1. Moles of EG

\rm n = 0.50 \times \text{4.70 gal} \times \dfrac{\text{3.785 L}}{\text{1  gal}} \times \dfrac{\text{1000 mL}}{\text{1 L}} \times \dfrac{\text{1.11 g}}{\text{1 mL}} \times \dfrac{\text{1 mol}}{\text{62.07 g}} = \text{159 mol}

2. Kilograms of water

m = 0.50 \times \text{4.70 gal} \times \dfrac{\text{3.785 L}}{\text{1  gal}} \times \dfrac{\text{998 g}}{\text{1 L}} \times \dfrac{\text{1 kg}}{\text{1000 g}} = \text{8.88 kg}

3. Molal concentration of EG

b =  \dfrac{\text{159 mol}}{\text{8.88 kg}} = \text{17.9 mol/kg}

4. Increase in boiling point

\rm \Delta T_{b} = iK_{b}b = 1 \times 0.512 \, \, ^{\circ}\text{C} \cdot kg \cdot mol^{-1} \, \times 17.9 \cdot mol \cdot kg^{-1} = 9.17 \, ^{\circ}\text{C}

5. Boiling point

\rm T_{b} = T_{b}^{\circ} + \Delta T_{b} = 100.00 \, ^{\circ}\text{C} + 9.17 \, ^{\circ}\text{C} = \mathbf{109.17 \, ^{\circ}C}\\\rm \text{The boiling point of the solution is $\large \boxed{\mathbf{109.17 \, ^{\circ}C}}$}

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