From the equation q=mCΔT, set the q of copper = to q of water,
So --- mCΔT(copper)=mCΔT(water).
mass (Cu - copper) = 38g
mass (H2O - water) = 15g
C (H2O) = 4.184 J/g*C
ΔΤ (H2O) = 33-22 = 11*C
ΔΤ (Cu) = 33-80 = -47*C (the final temp is the same for both materials - thermal equilibrium)
C (Cu) = ?
So --- 38(-47)C[Cu]=15(4.184)(11)
--- C[Cu]=690.36/(-1786) = 0.3865 J/g*C, or 0.39 in 2 sig figs. (The negative goes away, because specific heats are usually positive)
Ignoring the n's, there would only be one unpaired electron.
Carbon will have 4 valence electrons. It will have 2 in the p orbital and 2 in the s orbital. You can see this when you find the noble gas configuration of carbon which is [He]2s²2p² showing that carbon has 4 valence electrons.
I hope this helps. Let me know if anything is unclear.