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Darya [45]
3 years ago
5

Iron (II) sulfide reacts with hydrochloric acid according to the reaction: FeS(s) + 2 HCl(aq)→ FeCl2(s) + H2S(g) A reaction mixt

ure initially contains 0.223 mol FeS and 0.652 mol HCl. Once the reaction has occurred as completely as possible, what amount (in moles) of the excess reactant is left?
Chemistry
1 answer:
RideAnS [48]3 years ago
7 0

The amount ( in moles  of excess  reactant that is left is 0.206 moles


Explanation

FeS(s)  + 2HCl  (aq) →  FeCl2 (s)  + H2S (g)

  • by use of mole ratio of FeS: HCl which is  1:2 this means that  0.223 mole  of FeS  reacted  completely with 0.223   x   2/1 =0.446  moles  0f FeCl2.

  • HCl was in  excess because  0.446 moles of HCl reacted and initially  there was  0.652  moles.
  • Therefore the  amount that was left

      = 0.652- 0.446  =0.206  moles

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Answer:

7.38g HCl

Explanation:

Using H-H equation for acetic buffer:

pH = pKa + log [NaC2H3O2] / [HC2H3O2]

<em>Where pKa is -log Ka = 4.74 and [] could be taken as moles of each compound.</em>

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[NaC2H3O2]:

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[HC2H3O2]:

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That means total moles are:

[NaC2H3O2] + [HC2H3O2] = 0.57 moles <em>(1)</em>

And solving H-H equation for a pH of 4.21:

4.21 = 4.74 + log [NaC2H3O2] / [HC2H3O2]

0.29512 = [NaC2H3O2] / [HC2H3O2] <em>(2)</em>

Replacing (1) in (2):

0.29512 = 0.57mol - [HC2H3O2] / [HC2H3O2]

0.29512 [HC2H3O2] = 0.57mol - [HC2H3O2]

1.29512 [HC2H3O2] = 0.57mol

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The HCl reacts with NaC2H3O2 producing HC2H3O2, that means you need to add:

0.44 moles - 0.2375 moles =

0.2025 moles of HCl

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0.2025 moles * (36.45g/mol) =

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A mixture of calcium carbonate, CaCO3, and barium carbonate, BaCO3, weighing 5.40 g reacts fully with hydrochloric acid, HCl(aq)
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CaCO₃ = 85.18%

BaCO₃ = 14.82%

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The acid will react with the salts, the partial reactions are:

CaCO₃ + 2HCl → CaCl₂ + CO₂ + H₂O

BaCO₃ + 2HCl → BaCl₂ + CO₂ + H₂O

So, the total amount of CaCO₃ BaCO₃ will form the CO₂.

Using the ideal gas law to calculate the number of moles of CO₂:

PV = nRT, where P is the pressure, V is the volume, n is the number of moles, R is the gas constant (0.082 atm*L/mol*K), and T is the temperature (50ºC + 273 = 323 K).

0.904*1.39 = n*0.082*323

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The molar masses of the components are:

CaCO₃ = 40 g/mol of Ca + 12 g/mol of C + 3*16 g/mol of O = 100 g/mol

BaCO₃ = 137.3 g/mol of Ba + 12 g/mol of C + 3*16 g/mol of O = 197.3 g/mol

Let's call x the number of moles of CaCO₃ and y the number of moles of BaCO₃, so:

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100x + 197.3*(0.05 - x) = 5.4

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y = 0.004 mol of BaCO₃

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The percentages in the mixture are:

CaCO₃ = (4.60/5.40)*100% = 85.18%

BaCO₃ = (0.80/5.40)*100% = 14.82%

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