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PolarNik [594]
3 years ago
6

(Thermodynamics)

Chemistry
1 answer:
Setler79 [48]3 years ago
5 0

Answer:

456 kJ

Step-by-step explanation:

CH₄ + 2Cl₂ ⟶ CCl₄ + 2H₂ ; ΔH =  45.6 kJ

Treat the heat as if it were a product in the equation. Then use the molar ratio (45.6 kJ/2 mol Cl₂) in the usual way.

Amount of energy = 20 mol Cl₂ × (45.6 kJ/2 mol Cl₂)  = 456 kJ

You must add 456 kJ to react 20 mol of chlorine with excess methane.

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34. An electron in the 3d state of the hydrogen atom has a radial part of the wave function of the form A r2 exp(-r/3ao). What i
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Answer: Option (e) is the correct answer.

Explanation:

Formula to calculate radius is as follows.

          p(r) = Ar(r^{2}e^{\frac{-r}{3a_{o}}}

                = Ar^{3}e^{\frac{-r}{3a_{o}}}

     \frac{dp(r)}{dr} = 0

            Ar^{3}e^{\frac{-r}{3a_{o}}}(\frac{-1}{3a_{o}} + Ae^{\frac{-r}{3a_{o}}}(3r^{2}) = 0

                     \frac{Ar^{3}}{3a_{o}}e^{\frac{-r}{3a_{o}}}

                      = 3Ar^{2}e^{\frac{-r}{3a_{o}}}

                       r = 9a_{o}

Thus, we can conclude that most likely radius at which the electron would be found is 9a_{o}.

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Which career area in chemistry applies new discoveries to practical applications useful for consumers
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What do all nickel atoms have in common
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What characterizes a heterogeneous mixture?
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The normal boiling point of iodomethane, CH3I, is 42.43 8C, and its vapor pressure at 0.00 8C is 140. Torr. Calculate (a) the st
tigry1 [53]

Answer:

a=28600J; b=90.6 J/K; c=402 torr

Explanation:

(a) considering the data given

 Vapour pressure P1 =0  at Temperature T1 = 42.43˚C,

Vapour pressure P2 = 273.15 at Temperature T2= 315.58 K)

Using the Clausius-Clapeyron Equation

ln (P2/P1) = (ΔH/R)(1/T2 - 1/T1)

In 760/140 = ΔH/8.314 J/mol/K  × (1/315.58K -- 1/273.15K)

ΔH vap= +28.6 kJ/mol or 28600J

(b) using the Equation ΔG°=ΔH° - TΔS to solve forΔS.

Since ΔG at boiling point is zero,

ΔS =(ΔH°vap/Τb)

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= 90.6 J/K

(c) using ln (P2/P1) = (ΔH/R)(1/T2 - 1/T1)

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P298 K = 0.529 atm

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