Answers and Explanation:
a)- The chemical equation for the corresponden equilibrium of Ka1 is:
2. HNO2(aq)⇌H+(aq)+NO−2
Because Ka1 correspond to a dissociation equilibrium. Nitrous acid (HNO₂) losses a proton (H⁺) and gives the monovalent anion NO₂⁻.
b)- The relation between Ka and the free energy change (ΔG) is given by the following equation:
ΔG= ΔGº + RT ln Q
Where T is the temperature (T= 25ºc= 298 K) and R is the gases constant (8.314 J/K.mol)
At the equilibrium: ΔG=0 and Q= Ka. So, we can calculate ΔGº by introducing the value of Ka:
⇒ 0 = ΔGº + RT ln Ka
ΔGº= - RT ln Ka
ΔGº= -8.314 J/K.mol x 298 K x ln (4.5 10⁻⁴)
ΔGº= 19092.8 J/mol
c)- According to the previous demonstation, at equilibrium ΔG= 0.
d)- In a non-equilibrium condition, we have Q which is calculated with the concentrations of products and reactions in a non equilibrium state:
ΔG= ΔGº + RT ln Q
Q= ((H⁺) (NO₂⁻))/(HNO₂)
Q= ( (5.9 10⁻² M) x (6.7 10⁻⁴ M) ) / (0.21 M)
Q= 1.88 10⁻⁴
We know that ΔGº= 19092.8 J/mol, so:
ΔG= ΔGº + RT ln Q
ΔG= 19092.8 J/mol + (8.314 J/K.mol x 298 K x ln (1.88 10⁻⁴)
ΔG= -2162.4 J/mol
Notice that ΔG<0, so the process is spontaneous in that direction.
He was credited with discovering the subatomic particle also known as the electron in 1897.
Answer:
Bromine is a chemical element with the symbol Br and atomic number 35. It is the third-lightest halogen, and is a fuming red-brown liquid at room temperature that evaporates readily to form a similarly colored gas.
Answer:
The acid must be a concentrated acid
Explanation:
Ethene is prepared in the laboratory by heating ethanol with excess concentrated tetraoxosulphate VI acid at 170°C . The reactionoccursc in two stages;
1) when the ethanol and sulphuric acid are mixed in a ratio of 1:2, ethyl hydrogentetraoxosulpate VI is formed
2) The compound formed in the first step is heated in the presence of excess concentrated sulphuric acid to give ethene and sulphuric acid.
The overall reaction can be perceived as the dehydration of ethanol. The gas produced (ethene) is usually passed through sodium hydroxide solution to remove any gaseous impurities present.
concentrated sulphuric acid is used in this process since it is a good dehydrating agent.
