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BARSIC [14]
3 years ago
8

A student followed the procedure of this experiment to determine the solubility product of zinc(II) iodate, Zn(IO3)2. Solutions

of ZN(NO3)2 of known initial concentrations were titrated with 0.200 M KIO3 solutions to the first appearance of a white precipitate. The following data were collected.
Complete the table below and determine the solubility product constant.

[Zn(NO3)2]0, M Initial 0.226, 0.101 0.0452, 0.0118
[KIO3]0, M Titrant 0.200, 0.200, 0.200, 0.200
V0, mL of Zn(NO3)2 100.0, 100.0, 100.0, 100.0
V, mL of KIO3 titrant 12.9, 12.4, 13.0, 18.3

Chemistry
1 answer:
Fed [463]3 years ago
7 0

Answer:

Explanation:

Complete the table below and determine the solubility product constant.

[Zn(NO₃)₂] 0, M Initial 0.226, 0.101 0.0452, 0.0118

[KIO₃] 0, M Titrant 0.200, 0.200, 0.200, 0.200

V₀, mL of Zn(NO₃)₂100.0, 100.0, 100.0, 100.0

V, mL of KIO₃ titrant 12.9, 12.4, 13.0, 18.3

What needs to be determined are the following for each column/sample

V0 + V, mL

[Zn²⁺]  + [IO³⁻]    ⇄  [Zn²⁺][IO³⁻]2

log [Zn²⁺][IO³⁻]2

\frac{\sqrt{Zn^{2+}}}{1 + \sqrt{Zn^{2+}}}

Then there's the determination of Ksp itself

log Ksp =  Ksp of Zn(IO3)2 =

Considering this, which of the ion products is closest to Ksp, and why?

Finally, the titration volumes for the first three samples don't vary greatly. However the last sample is considerably larger. Why is this to be expected?

The attached figures shed more light on the solution to this problem

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For each set of values, calculate the missing variable using the ideal gas law.
allsm [11]

Answer:

1. n = 0.174mol

2. T= 26.8K

3. P = 1.02atm

4. V = 126.88L

Explanation:

1. P= 2.61atm

V = 1.69L

T = 36.1 °C = 36.1 + 273= 309.1K

R = 0.082atm.L/mol /K

n =?

n = PV / RT = (2.61x1.69)/(0.082x309.1)

n = 0.174mol

2. P = 302 kPa = 302000Pa

101325Pa = 1atm

302000Pa = 302000/101325 = 2.98atm

V = 2382 mL = 2.382L

T =?

n = 3.23 mol

R = 0.082atm.L/mol /K

T= PV /nR = (2.98x2.382)/(3.23x0.082) = 26.8K

3. P =?

V = 0.0250 m³ = 25L

T = 288K

n = 1.08mol

R = 0.082atm.L/mol /K

P = nRT/V = (1.08x0.082x288)/25 = 1.02atm

4. P = 782 torr

760Torr = 1 atm

782 torr = 782/760 = 1.03atm

V =?

T = 303K

n = 5.26 mol

R = 0.082atm.L/mol /K

V = nRT/P

V = (5.26x0.082x303)/1.03 = 126.88L

8 0
3 years ago
Determine the mass of CuSO4 • 5H20 that must be used to prepare 250mL of 2.01 M CuSO4(aq).
mario62 [17]

Given parameters:

Volume of CuSO₄ = 250mL

Concentration of CuSO₄ = 2.01M

Unknown:

Mass of CuSO₄.5H₂O = ?

To solve this problem, we must write the chemical relationship between both species.;

             CuSO₄.5H₂O  →   CuSO₄ + 5H₂O

Now that we know the expression, it is possible to solve for the unknown mass.

First find the number of moles of CuSO₄;

         Number of moles  = Concentration x Volume

Take 250mL to L so as to ensure uniformity of units;

           Volume  = 250 x 10⁻³L

  Input the parameters and solve for number of moles;

        Number of moles  = 250 x 10⁻³  x  2.01 = 0.5mol

From the equation;

             1 mole of CuSO₄ is produced from 1 mole of CuSO₄.5H₂O  

So  0.5 moles of CuSO₄ will be produced from 0.5 moles of CuSO₄.5H₂O

Now let us find the molar mass of CuSO₄.5H₂O = 63.6 + 32 + 4(16) + 5(2x1 + 16)  = 249.6g/mole

Mass of CuSO₄.5H₂O = number of moles x molar mass

                                      = 0.5 x 249.6

                                     = 124.8g

The mass of CuSO₄.5H₂O is 124.8g

5 0
3 years ago
What is the easiest way to explain molecular compounds and covalent bonds also adding information about valance electrons?
wlad13 [49]

Answer:

Molecular compounds consist of two or more nonmetals. The nonmetals that make up a molecular compound are held together by covalent/molecular bonds. Covalent bonds is known as the "sharing" of valence electrons between two or more chemical species. Valence electrons are shared so that the atoms of the compound can become stable, much like how ionic bonds transfer valence electrons between atoms to achieve stability.

5 0
3 years ago
2. What pressure is required to compress 196.0 L of air at 1.00 atmosphere into a cylinder
damaskus [11]

Answer:

<h2>7.54 atm </h2>

Explanation:

The required pressure can be found by using the formula for Boyle's law which is

P_2 =  \frac{P_1V_1}{V_2}  \\

where

P1 is the initial pressure

P2 is the final pressure

V1 is the initial volume

V2 is the final volume

From the question we have

P_2 =  \frac{1 \times 196}{26}  =  \frac{196}{26}   \\ = 7.538461...

We have the final answer as

<h3>7.54 atm </h3>

Hope this helps you

3 0
2 years ago
Is nuclear energy potential or kinetic energy?
astraxan [27]

Answer:

kenitic energy

Explanation:

7 0
3 years ago
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