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BARSIC [14]
3 years ago
8

A student followed the procedure of this experiment to determine the solubility product of zinc(II) iodate, Zn(IO3)2. Solutions

of ZN(NO3)2 of known initial concentrations were titrated with 0.200 M KIO3 solutions to the first appearance of a white precipitate. The following data were collected.
Complete the table below and determine the solubility product constant.

[Zn(NO3)2]0, M Initial 0.226, 0.101 0.0452, 0.0118
[KIO3]0, M Titrant 0.200, 0.200, 0.200, 0.200
V0, mL of Zn(NO3)2 100.0, 100.0, 100.0, 100.0
V, mL of KIO3 titrant 12.9, 12.4, 13.0, 18.3

Chemistry
1 answer:
Fed [463]3 years ago
7 0

Answer:

Explanation:

Complete the table below and determine the solubility product constant.

[Zn(NO₃)₂] 0, M Initial 0.226, 0.101 0.0452, 0.0118

[KIO₃] 0, M Titrant 0.200, 0.200, 0.200, 0.200

V₀, mL of Zn(NO₃)₂100.0, 100.0, 100.0, 100.0

V, mL of KIO₃ titrant 12.9, 12.4, 13.0, 18.3

What needs to be determined are the following for each column/sample

V0 + V, mL

[Zn²⁺]  + [IO³⁻]    ⇄  [Zn²⁺][IO³⁻]2

log [Zn²⁺][IO³⁻]2

\frac{\sqrt{Zn^{2+}}}{1 + \sqrt{Zn^{2+}}}

Then there's the determination of Ksp itself

log Ksp =  Ksp of Zn(IO3)2 =

Considering this, which of the ion products is closest to Ksp, and why?

Finally, the titration volumes for the first three samples don't vary greatly. However the last sample is considerably larger. Why is this to be expected?

The attached figures shed more light on the solution to this problem

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2 years ago
A solution is made by combining 500 mL of 0.10 M HF (Ka=7.2 x 10^-4) with 300 mL of 0.15 M NaF. What is the pH of the resulting
n200080 [17]

Answer:

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Explanation:

HF ⇄ H + + F

Using Henderson-Hasselbalch Equation:

pH = pKa + log [A-]/[HA].

Where;

pKa = Dissociation constant = -log Ka

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[HA] = concentration of the acid = moles of acid/total volume

             = 0.10 x 0.5/0.8

                    = 0.0625 M

Note: <em>Total volume = 500 + 300 = 800 mL = 0.8 dm3</em>

pH = 3.14266 + log [0.05625/0.0625]

      = 3.14267 + (-0.04575749056)

           = 3.09691250944

<em>From all the available options below:</em>

<em>a) 2.97 </em>

<em>b) 3.10 </em>

<em>c) 3.19 </em>

<em>d) 3.22 </em>

<em>e) 3.32</em>

The correct option is b.

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Bas_tet [7]

Total vapor pressure can be calculated using partial vapor pressures and mole fraction as follows:

P=X_{A}P_{A}+X_{B}P_{B}

Here, X_{A} is mole fraction of A, X_{B} is mole fraction of B, P_{A} is partial pressure of A and P_{B} is partial pressure of B.

The mole fraction of A and B are related to each other as follows:

X_{A}+X_{B}=1

In this problem, A is hexane and B is octane, mole fraction of hexane is given 0.580 thus, mole fraction of octane can be calculated as follows:

X_{octane}=1-X_{hexane}=1-0.58=0.42

Partial pressure of hexane and octane is given 183 mmHg and 59.2 mmHg respectively.

Now, vapor pressure can be calculated as follows:

P=X_{hexane}P_{hexane}+X_{octane}P_{octane}

Putting the values,

P=(0.580)(183 mmHg)+(0.420)(59.2 mmHg)=131 mmHg

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Answer:

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