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Darina [25.2K]
3 years ago
12

Using the following standard reduction potentials, Fe3+(aq) + e- → Fe2+(aq) E° = +0.77 V Ni2+(aq) + 2 e- → Ni(s) E° = -0.23 V ca

lculate the standard cell potential for the galvanic cell reaction given below, and determine whether or not this reaction is spontaneous under standard conditions. Ni2+(aq) + 2 Fe2+(aq) → 2 Fe3+(aq) + Ni(s)
Chemistry
1 answer:
lina2011 [118]3 years ago
3 0

<u>Answer:</u> The above reaction is non-spontaneous.

<u>Explanation:</u>

For the given chemical reaction:

Ni^{2+}(aq.)+2Fe^{2+}(aq.)\rightarrow 2Fe^{3+}(aq.)+Ni(s)

Here, nickel is getting reduced because it is gaining electrons and iron is getting oxidized because it is loosing electrons.

We know that:

E^o_{(Fe^{3+}/Fe^{2+})}=0.77V\\E^o_{(Ni^{2+}/Ni)}=-0.23V

Substance getting oxidized always act as anode and the one getting reduced always act as cathode.

To calculate the E^o_{cell} of the reaction, we use the equation:

E^o_{cell}=E^o_{cathode}-E^o_{anode}

E^o_{cell}=-0.23-0.77=-1.0V

Relationship between standard Gibbs free energy and standard electrode potential follows:

\Delta G^o=-nFE^o_{cell}

As, the standard electrode potential of the cell is coming out to be negative for the above cell. Thus, the standard Gibbs free energy change of the reaction will become positive making the reaction non-spontaneous.

Hence, the above reaction is non-spontaneous.

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Calculate the number of kilojoules to warm 125 g of iron from 23.5 °C to 78.0 °C.
insens350 [35]
Given:
Iron, 125 grams T
1 = 23.5 degrees Celsius, T2 = 78 degrees Celsius.  

Required:
Heat produced in kilojoules  

Solution:
The molar mass of iron is 55.8 grams per mole. SO we need to change the given mass of iron into moles.  
 
Number of moles of iron = 125 g/(55.8 g/mol) = 2.24 moles  
<span>
Q (heat) = nRT = nR(T2 = T1)</span>
Q (heat) = 2.24 moles (8.314 Joules per mol degrees Celsius) (78.0 degrees Celsius – 23.5 degrees Celsius)
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grigory [225]

In a chemical reaction, 0. 3 moles of H2O result in the production of 0.2 moles of CO2. Chemical reactions are the means through which one group of chemical compounds are changed into another.

Chemical reactions are typically defined as changes that only affect the positions of electrons in the formation and breakage of chemical bonds between atoms, with no change to the nuclei (i.e., no change to the elements present). These types of changes are often included in the term chemical reactions.

Number of moles Definition We utilize this enormous quantity to measure atoms. Additionally, it equals the 6.022* 10 23 atoms that make up 12 grammes of carbon-12, or atoms.

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