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Nady [450]
3 years ago
7

Calculate the pH of a solution that is 0.210 M in nitrous acid (HNO2) and 0.290 M in potassium nitrite (KNO2). The acid dissocia

tion constant of nitrous acid is 4.50 × 10-4.
Chemistry
1 answer:
jeka943 years ago
6 0

Answer:

pH = 3.49

Explanation:

We have a buffer system formed by a weak acid (HNO₂) and its conjugate base (NO₂⁻ coming from KNO₂). We can calculate the pH  of a buffer ssytem using the Henderson-Hasselbach equation.

pH = pKa + log [base] / [acid]

pH = -log Ka + log [NO₂⁻] / [HNO₂]

pH = -log 4.50 × 10⁻⁴ + log 0.290 M / 0.210 M

pH = 3.49

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8 0
3 years ago
Lead(II) nitrate and ammonium iodide react to form lead(II) iodide and ammonium nitrate according to the reaction Pb(NO3)2(aq)+2
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Answer:

a) volume of ammonium iodide required =349 mL

b) the moles of lead iodide formed = 0.0436 mol

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The reaction is:

Pb(NO_{3})_{2}+2NH_{4}I -->PbI_{2}+2NH_{4}NO_{3}

It shows that one mole of lead nitrate will react with two moles of ammonium iodide to give one mole of lead iodide.

Let us calculate the moles of lead nitrate taken in the solution.

Moles=molarityX volume (L)

Moles of lead nitrate = 0.360 X 0.121 =0.0436 mol

the moles of ammonium iodide required = 2 X0.0436 = 0.0872 mol

The volume of ammonium iodide required will be:

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7 0
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