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polet [3.4K]
3 years ago
10

Assuming that all the energy given off in the reaction goes to heating up only the air in the house, determine the mass of metha

ne required to heat the air in a house by 10.0 ∘C. Assume each of the following: house dimensions are 35.0 m × 35.0 m × 3.2 m ; specific heat capacity of air is 30 J/K⋅mol; 1.00 mol of air occupies 22.4L for all temperatures concerned.
Chemistry
1 answer:
nirvana33 [79]3 years ago
3 0

Answer:

0.92 kg

Explanation:

The volume occupied by the air is:

35.0m\times 35.0m \times 3.2m \times \frac{10^{3}L }{1m^{3} } =3.9 \times 10^{6} L

The moles of air are:

3.9 \times 10^{6} L \times \frac{1.00mol}{22.4L} =1.7 \times 10^{5}mol

The heat required to heat the air by 10.0 °C (or 10.0 K) is:

1.7 \times 10^{5}mol \times \frac{30J}{K.mol} \times 10.0 K = 5.1 \times 10^{7}J

Methane's heat of combustion is 55.5 MJ/kg. The mass of methane required to heat the air is:

5.1 \times 10^{7}J \times \frac{1kgCH_{4}}{55.5 \times 10^{6} J } =0.92kgCH_{4}

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Explanation:

<u>1) First law of thermodynamic (energy balance)</u>

  • Heat released by the the hot water (345K ) = Heat absorbedby the cold water (298 K) + Heat absorbed by the calorimeter

<u>2) Energy change of each substance:</u>

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       Heat₁ = 49.9 g × 1 cal / g°C × (345 K - 317 K) = 49.9 g × 1 cal / g°C × (28K)

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Ccal = 23.6 cal/ K

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  • 1 cal = 4.18 Joule

       23.6 cal / K × 4.18 J / cal = 98.6 J/K

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