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Zielflug [23.3K]
3 years ago
12

A sample containing 2.30 mol of Ne gas has an initial volume of 8.00 L. What is the final volume, in liters, when the following

changes occur in the quantity of the gas at constant pressure and temperature?a. A leak allows one-half of Ne atoms to escape.b. A sample of 3.50 mol of Ne is added to the 2.30 mol of Ne gas in the container.c. A sample of 25.0 g of Ne is added to the 2.30 mol of Ne gas in the container.
Chemistry
1 answer:
marta [7]3 years ago
6 0

Answer:

a. 4,00L

b. 16,00L

c. 12,31L

Explanation:

Avogadro's law says:

\frac{V_1}{n_1} =\frac{V_2}{n_2}

a. If initial conditions are 2,30mol and 8,00L and you lose one-half of atoms, that means you have 1,15mol:

\frac{8,00L}{2,30mol} =\frac{V_2}{1,15mol}

<em>V₂ = 4,00L</em>

b. If initial conditions are 2,30mol and 8,00L and you add 2,30mol, that means you have 4,60mol:

\frac{8,00L}{2,30mol} =\frac{V_2}{4,60mol}

<em>V₂ = 16,00L</em>

c. 25,0g of Ne are:

25,0g × (1mol / 20,1797g) = 1,24 moles of Ne. That means you have 2,30mol - 1,24mol = 3,54mol of Ne

\frac{8,00L}{2,30mol} =\frac{V_2}{3,54mol}

<em>V₂ = 12,31L</em>

I hope it helps!

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A voltaic cell consists of a Pb/Pb2+ half-cell and a Cu/Cu2+ half-cell at 25 ?C. The initial concentrations of Pb2+ and Cu2+ are
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Answer:

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b) Ecell =  0.4695 V

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Explanation:

a)

The reaction at the cathode is represented as follows:

Cu2 + + 2e- -> Cu (s) Eocathode = 0.34 V

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The number of moles of the electrons that are involved is equal to n = 2

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 The initial cell potential can be calculated with the following formula:

Ecell = Eocell - - 0.0592 / n) log ([(Pb2 +)] / [(Cu2 +)]) = 0.47 - (0.0592 / 2) log (0.052 / 1.4) = 0.5123 V

b)

The reaction in the cell is equal to:

Cu2 + + Pb (s) -> Cu (s) + Pb2 +

The concentration of Cu2 that gives the exercise is equal 0.2 M

Therefore, the change in concentration for Cu2 + is equal to:

Cu2 + = 1.4 M - 0.2 M = 1.2 M

We use the formula from part a)

Ecell = Eocell - (0.0592 / n) log ([(Pb2 +)] / [(Cu2 +)]) = 0.47 - (0.0592 / 2) log (1,252 / 1.2) = 0.4695 V

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To find the concentration of Pb2 + when there is a potential change in the cell of 0.37 V, we must clear the concentration of Pb2 + from the following formula:

Eccell = Echocell - (0.0592 / n) log (([Pb2 +]) / ([Cu2 +]))

0.0296 log ([Pb2 +] / [Cu2 +]) = (Eocélula - Ecélula / 0.0296)

Clearing Pb2 +:

[Pb2 +] = 4.75 M

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Answer:

1) The partial pressure of SO₂ gas in the larger container = 0.115 atm.

2) The partial pressure of N₂ gas in the larger container = 0.206 atm.

3) The total pressure in the vessel = 0.321 atm.

Explanation:

  • To calculate the partial pressure of each gas, we can use the general law of ideal gas: PV = nRT.

where, P is the partial pressure of the gas in atm,

V is the volume of the vessel in L,

n is the no. of moles of the gas,

R is the general gas constant (R = 0.082 L.atm/mol.K),

T is the temperature of the gas in K.

<u><em>1) What is the partial pressure of SO₂ gas in the larger container?</em></u>

<em>∵ P = nRT/V.</em>

n = mass/molar mass = (3.0 g)/(64.066 g/mol) = 0.047 mol.

R = 0.082 L.atm/mol.K.

T = 26 °C + 273.15 = 299.15 K.

V = 10.0 L. (The volume of the new container)

∴ P = nRT/V = (0.047 mol)(0.082 L.atm/mol.K)(299.15 K)/(10.0 L) = 0.115 atm.

<u><em>2) What is the partial pressure of N₂ gas in the larger container?</em></u>

<em>∵ P = nRT/V.</em>

n = mass/molar mass = (2.35 g)/(28.0 g/mol) = 0.084 mol.

R = 0.082 L.atm/mol.K.

T = 26 °C + 273.15 = 299.15 K.

V = 10.0 L. (The volume of the new container)

∴ P = nRT/V = (0.084 mol)(0.082 L.atm/mol.K)(299.15 K)/(10.0 L) = 0.206 atm.

<u><em>3) What is the total pressure in the vessel?</em></u>

  • According to Dalton's law the total pressure exerted is equal to the sum of the partial pressures of the individual gases.

<em>∵ The total pressure in the vessel = the partial pressure of SO₂ + the partial pressure of N₂.</em>

∴ The total pressure in the vessel = 0.115 + 0.206 = 0.321 atm.

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