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Zanzabum
3 years ago
14

Calculate the work done when an ideal gas expands isothermally and reversibly in a piston and cylinder assembly for expansion of

a gas at 300 K from initial pressure 10 bar to final pressure 1 bar.
Chemistry
1 answer:
pantera1 [17]3 years ago
5 0

Answer:

W=5743.1077\ J

Explanation:

The expression for the work done is:

W=RT \ln \left( \dfrac{P_1}{P_2} \right)

Where,

W is the amount of work done by the gas

R is Gas constant having value = 8.314 J / K mol

T is the temperature

P₁ is the initial pressure

P₂ is the final pressure

Given that:

T = 300 K

P₁ = 10 bar

P₂ = 1 bar

Applying in the equation as:

W=8.314\times 300 \ln \left( \dfrac{10}{1} \right)

W=300\times \:8.314\ln \left(10\right)

W=2.30258\times \:2494.2

W=5743.1077\ J

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maks197457 [2]

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<u>Explanation:</u>

The number of moles is defined as the ratio of the mass of a substance to its molar mass.  The equation used is:

\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}} ......(1)

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Given mass of hexane = 1.72 g

Molar mass of hexane = 86.18 g/mol

Putting values in equation 1, we get:

\text{Moles of hexane}=\frac{1.72g}{86.18g/mol}=0.020mol

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Given mass of oxygen gas = 8.0 g

Molar mass of oxygen gas= 32 g/mol

Putting values in equation 1, we get:

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2C_6H_{14}+19O_2\rightarrow 12CO_2+14H_2O

By stoichiometry of the reaction:

If 2 moles of hexane reacts with 19 moles of oxygen gas

So, 0.020 moles of hexane will react with = \frac{19}{2}\times 0.020=0.19mol of oxygen gas

As the given amount of oxygen gas is more than the required amount. Thus, it is present in excess and is considered as an excess reagent.

Thus, hexane is considered a limiting reagent because it limits the formation of the product.

By the stoichiometry of the reaction:

If 2 moles of hexane produces 14 moles of H_2O

So, 0.020 moles of hexane will produce = \frac{14}{2}\times 0.020=0.14mol of H_2O

We know, molar mass of H_2O = 18 g/mol

Putting values in above equation, we get:

\text{Mass of }H_2O=(0.14mol\times 18g/mol)=2.52g

Hence, the mass of H_2O produced is 2.52 g

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