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gregori [183]
3 years ago
8

hydrogen-2 is also known as deuterium as well as hydrogen-3 is known as tritium hydrogen-1 is our common hydrogen isotope a samp

le hydrogen gas has 99% hydrogen -1 ,0.8% deuterium , and 0.2% tritium what is the average atomic mass of this mixture of isotope to the thousands place
Chemistry
1 answer:
UkoKoshka [18]3 years ago
6 0
H-1 only has 1 proton and 1 electron, so its mass number is 1.
H-2 has one more neutron so its mass number is 2
H-3 has one more neutron than H-2 so its mass number will be 3.
average atomic mass = 1 x 99% + 2 x 0.8% + 3 x 0.2%
=1.012
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From the value Kf=1.2×109 for Ni(NH3)62+, calculate the concentration of NH3 required to just dissolve 0.016 mol of NiC2O4 (Ksp
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<u>Answer:</u> The concentration of NH_3 required will be 0.285 M.

<u>Explanation:</u>

To calculate the molarity of NiC_2O_4, we use the equation:

\text{Molarity of the solution}=\frac{\text{Moles of solute}}{\text{Volume of solution (in L)}}

Moles of NiC_2O_4 = 0.016 moles

Volume of solution = 1 L

Putting values in above equation, we get:

\text{Molarity of }NiC_2O_4=\frac{0.016mol}{1L}=0.016M

For the given chemical equations:

NiC_2O_4(s)\rightleftharpoons Ni^{2+}(aq.)+C_2O_4^{2-}(aq.);K_{sp}=4.0\times 10^{-10}

Ni^{2+}(aq.)+6NH_3(aq.)\rightleftharpoons [Ni(NH_3)_6]^{2+}+C_2O_4^{2-}(aq.);K_f=1.2\times 10^9

Net equation: NiC_2O_4(s)+6NH_3(aq.)\rightleftharpoons [Ni(NH_3)_6]^{2+}+C_2O_4^{2-}(aq.);K=?

To calculate the equilibrium constant, K for above equation, we get:

K=K_{sp}\times K_f\\K=(4.0\times 10^{-10})\times (1.2\times 10^9)=0.48

The expression for equilibrium constant of above equation is:

K=\frac{[C_2O_4^{2-}][[Ni(NH_3)_6]^{2+}]}{[NiC_2O_4][NH_3]^6}

As, NiC_2O_4 is a solid, so its activity is taken as 1 and so for C_2O_4^{2-}

We are given:

[[Ni(NH_3)_6]^{2+}]=0.016M

Putting values in above equations, we get:

0.48=\frac{0.016}{[NH_3]^6}}

[NH_3]=0.285M

Hence, the concentration of NH_3 required will be 0.285 M.

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