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3 years ago

Was the acetylacetone miscible with water? What about if NH3 is added to the solution? Why?

Chemistry

1 answer:

luda_lava [24]3 years ago

4 0

Answer:

See explanation

Explanation:

The compound is acetylacetone. This compound is immiscible with water because it is completely nonpolar.

However the introduction of ammonia, leads to the ionization of the specie. In the presence of a base(such as NH3), the molecule acetylacetone is deprotonated and its corresponding anion is formed. This anion can now interact with water and become miscible with it.

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LenaWriter [7]

Answer:

I say the second one, im not rlly sure tho

Explanation:

5 0

2 years ago

The unit cell for cr2o3 has hexagonal symmetry with lattice parameters a = 0.4961 nm and c = 1.360 nm. If the density of this ma

IRINA_888 [86]

To calculate the packing factor, first calculate the area and volume of unit cell.

Area is calculated as:

$A=6R^{2}\sqrt{3}$

Here, R is radius and is related to a as follows:

$R=\frac{a}{2}$

Putting the value in expression for area,

$A=6(\frac{a}{2})^{2}\sqrt{3}=1.5a^{2}\sqrt{3}$

The value of a is 0.4961 nm

Since, $1 nm=10^{-7}cm$

Thus, $0.4961 nm=4.961\times 10^{-8} cm$

Putting the value,

$Area=1.5(4.961\times 10^{-8}cm)^{2}\sqrt{3}=6.39\times 10^{-15}cm^{2}$

Now, volume can be calculated as follows:

$V=Area\times c$

The value of c is 1.360 nm or $1.360\times 10^{-7} cm$

Putting the value,

$V=(6.39\times 10^{-15}cm^{2})\times (1.360\times 10^{-7} cm)=8.7\times 10^{-22}cm^{3}$

now, number of atom in unit cell can be calculated by using the following formula:

$n=\frac{\rho N_{A}V_{c}}{A}$

Here, A is atomic mass of $Cr_{2}O_{3}$ is 151.99 g/mol.

Putting all the values,

$n=\frac{(5.22 g/cm^{3})(6.023\times 10^{23} mol^{-1})(8.7\times 10^{-22}cm^{3})}{(151.99 g/mol)}\approx 18$

Thus, there will be 18 $Cr_{2}O_{3}$ units in 1 unit cell.

Since, there are 2 Cr atoms and 3 oxygen atoms thus, units of chromium and oxygen will be 2×18=36 and 3×18=54 respectively.

The atomic radii of $Cr^{3+}$ and $O^{2-}$ is 62 pm and 140 pm respectively.

Converting them into cm:

$1 pm=10^{-10}cm$

Thus,

$r_{Cr^{3+}}=6.2\times 10^{-9}cm$

and,

$r_{O^{2-}}=1.4\times 10^{-8}cm$

Volume of sphere will be sum of volume of total number of cations and anions thus,

$V_{S}=V_{Cr^{3+}}+V_{O^{2-}}$

Since, volume of sphere is $V=\frac{4}{3}\pi r^{3}$ ,

$V_{S}=36\left ( \frac{4}{3}\pi (r_{Cr^{3+})^{3}} \right )+54\left ( \frac{4}{3}\pi (r_{O^{2-})^{3}} \right )$

Putting the values,

$V_{S}=36\left ( \frac{4}{3}(3.14) (6.2\times 10^{-9} cm)^{3}} \right )+54\left ( \frac{4}{3}(3.14) (1.4\times 10^{-8} cm)^{3}} \right )=6.6\times 10^{-22}\times 10^{-8}cm^{3}$

The atomic packing factor is ratio of volume of sphere and volume of crystal, thus,

$packing factor=\frac{V_{S}}{V_{C}}=\frac{6.6\times 10^{-22}cm^{3}}{8.7\times 10^{-22}cm^{3}}=0.758$

Thus, atomic packing factor is 0.758.

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3 years ago

Read 2 more answers

For an atom’s electrons, how many energy sublevels are present in the principal energy level n = 4?

jekas [21]

In this question given concerning the atom's electron, the number of energy sublevels present in the principal energy level n = 4 is to be determined. For this matter, it should be remembered that the number of sublevels of a certain principal energy level is equal to n. For this item, the number of sublevels is also 4. That is s, p, d and f.

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3 years ago

Read 2 more answers

A) The equilibrium shifts to the left, producing more H3O+.

Lunna [17]

Answer: these are just options, what is the main question, without it, we cannot determine which option is correct, so please repost the question.

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3 years ago

Which of the following correctly<br> identifies segment XY and why?

Alecsey [184]

Answer:

sh1t

Explanation:

sh1t yummy

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3 years ago