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Marrrta [24]
3 years ago
7

Was the acetylacetone miscible with water? What about if NH3 is added to the solution? Why?

Chemistry
1 answer:
luda_lava [24]3 years ago
4 0

Answer:

See explanation

Explanation:

The compound is acetylacetone. This compound is immiscible with water because it is completely nonpolar.

However the introduction of ammonia, leads to the ionization of the specie. In the presence of a base(such as NH3), the molecule acetylacetone is deprotonated and its corresponding anion is formed. This anion can now interact with water and become miscible with it.

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How many moles are present in a 24.5 gram sample of K2Cr2O7?
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the concentration of the radio active isotope potassium-40 in a rock sample is found to be 6.25%. what is the age of the rock
julsineya [31]

Answer:

5.0 x 10⁹ years.

Explanation:

  • It is known that the decay of a radioactive isotope isotope obeys first order kinetics.
  • Half-life time is the time needed for the reactants to be in its half concentration.
  • If reactant has initial concentration [A₀], after half-life time its concentration will be ([A₀]/2).
  • Also, it is clear that in first order decay the half-life time is independent of the initial concentration.
  • The half-life of K-40 = 1.251 × 10⁹ years.

  • For, first order reactions:

<em>k = ln(2)/(t1/2) = 0.693/(t1/2).</em>

Where, k is the rate constant of the reaction.

t1/2 is the half-life of the reaction.

∴ k =0.693/(t1/2) = 0.693/(1.251 × 10⁹ years) = 5.54 x 10⁻¹⁰ year⁻¹.

  • Also, we have the integral law of first order reaction:

<em>kt = ln([A₀]/[A]),</em>

where, k is the rate constant of the reaction (k = 5.54 x 10⁻¹⁰ year⁻¹).

t is the time of the reaction (t = ??? year).

[A₀] is the initial concentration of (K-40) ([A₀] = 100%).

[A] is the remaining concentration of (K-40) ([A] = 6.25%).

∴ (5.54 x 10⁻¹⁰ year⁻¹)(t) = ln((100%)/( 6.25%))

∴ (5.54 x 10⁻¹⁰ year⁻¹)(t) = 2.77.

∴ t = 2.77/(5.54 x 10⁻¹⁰ year⁻¹) = 5.0 x 10⁹ years.

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