Answer:
(B) F⁻, HCOOH
Explanation:
(A) CH₄, HCOOH
(B) F⁻, HCOOH
(C) F⁻, CH₃-O-CH₃
The hydrogen bonds are formed when the hydrogen is found between two electronegative atoms such as oxygen (O), nitrogen (N) or florine (F).
O····H-O, F····H-O, O····H-N
(A) CH₄, HCOOH
- here methane CH₄ is not capable to form hydrogen bond with water
- formic acid HCOOH can form hydrogen bonds with water
H-C(=O)-O-H····OH₂
(B) F⁻, HCOOH
-both floride (F⁻) and formic acid can form hydrogen bonds with water
F····OH₂
H-C(=O)-O-H····OH₂
(C) F⁻, CH₃-O-CH₃
- dimethyl-ether CH₃-O-CH₃ is not capable to form hydrogen bond with water
- floride (F⁻) can form hydrogen bonds with water
F····OH₂
Density/Earth’s gravitational pull.
Answer:
(3R,4R)-4-bromohexan-3-ol
Explanation:
In this case, we have reaction called <u>halohydrin formation</u>. This is a <u>markovnikov reaction</u> with <u>anti configuration</u>. Therefore the halogen in this case "Br" and the "OH" must have <u>different configurations</u>. Additionally, in this molecule both carbons have the <u>same substitution</u>, so the "OH" can go in any carbon.
Finally, in the product we will have <u>chiral carbons</u>, so we have to find the absolute configuration for each carbon. On carbon 3 we will have an "R" configuration on carbon 4 we will have also an "R" configuration. (See figure 1)
I hope it helps!
<h3><em><u>solution</u></em><em><u>:</u></em></h3>
<em><u>The initial entropy is obtained from the initial pressure and temperature with data from A-6 using interpolation:</u></em>
<em><u>s</u></em><em><u>=</u></em><em><u> </u></em><em><u>8</u></em><em><u>.</u></em><em><u>26</u></em><em><u>5</u></em><em><u>2</u></em><em><u> </u></em><em><u>kJ</u></em><em><u>/</u></em><em><u>kgK</u></em>
<em><u>The final temperature is determined from the entropy and the final pressure with data from A-6 using interpolation:</u></em>
<em><u>T₂ = T₁+</u></em><em><u> </u></em><em><u>T₂ - </u></em><em><u>T₁</u></em><em><u>/</u></em><em><u> </u></em><em><u>8</u></em><em><u>₂</u></em><em><u> </u></em><em><u>-</u></em><em><u> </u></em><em><u>8</u></em><em><u>₁</u></em><em><u> </u></em><em><u>(</u></em><em><u> </u></em><em><u>s</u></em><em><u> </u></em><em><u>-</u></em><em><u> </u></em><em><u>s</u></em><em><u>₁</u></em><em><u>)</u></em>
<em><u>= </u></em><em><u>(</u></em><em><u>400 +</u></em><em><u> </u></em><em><u>500 - 400</u></em><em><u>/</u></em><em><u>8.3271</u></em><em><u> </u></em><em><u>-</u></em><em><u> </u></em><em><u>8.0347</u></em><em><u> </u></em><em><u>(8.2652 - 8</u></em><em><u>)</u></em><em><u>)</u></em>
<em><u>= 478.83°C</u></em>
<em><u>The final enthalpy is determined in the same way:</u></em>
<em><u>h₂= h₁</u></em><em><u> </u></em><em><u>+</u></em><em><u> </u></em><em><u>h₂</u></em><em><u> </u></em><em><u>-</u></em><em><u> </u></em><em><u>h₁</u></em><em><u>/</u></em><em><u>s</u></em><em><u>₂</u></em><em><u> </u></em><em><u>-</u></em><em><u> </u></em><em><u>s</u></em><em><u>₁</u></em><em><u> </u></em><em><u>( s - s₁)</u></em>
<em><u>= (</u></em><em><u> </u></em><em><u>3275.5</u></em><em><u>+</u></em><em><u> </u></em><em><u>3486.6 </u></em><em><u>-</u></em><em><u> </u></em><em><u>3275.5</u></em><em><u>/</u></em><em><u> </u></em><em><u>8.3271</u></em><em><u> </u></em><em><u>-</u></em><em><u> </u></em><em><u>8.0347</u></em><em><u>)</u></em><em><u> </u></em><em><u>(8.265</u></em><em><u>)</u></em>
<em><u>=</u></em><em><u> </u></em><em><u>3441.91 </u></em><em><u>kJ</u></em><em><u>/</u></em><em><u>kg</u></em>
I believe those all look correct!