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Sati [7]
3 years ago
9

consider the following equilibrium:h2co3(aq) h2o(l) h3o (aq) hco3-1(aq).what is the correct equilibrium expression?

Chemistry
1 answer:
MAVERICK [17]3 years ago
4 0

The equilibrium expression shows the ratio between products and reactants. This expression is equal to the concentration of the products raised to its coefficient divided by the concentration of the reactants raised to its coefficient. The correct equilibrium expression for the given reaction is:<span>

<span>H2CO3(aq) + H2O(l) = H3O+(aq) + HCO3-1(aq)

Kc = [HCO3-1] [H3O+] / [H2O] [H2CO3]</span></span>

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<em>∵ ΔTf = iKf.m</em>

where, <em>i</em> is the van 't Hoff factor.

<em>Kf </em>is the molal depression freezing constant.

<em>m</em> is the molality of the solute.

<em>The van 't Hoff factor is the ratio between the actual concentration of particles produced when the substance is dissolved and the concentration of a substance as calculated from its mass. </em>

<em></em>

  • For most non-electrolytes dissolved in water, the van 't Hoff factor is essentially 1.

<em>So, for sugar: i = 1.</em>

<em>∴ ΔTf for sugar = iKf.m = (1)(Kf)(2.0 m) = 2 Kf.</em>

<em></em>

  • For most ionic compounds dissolved in water, the van 't Hoff factor is equal to the number of discrete ions in a formula unit of the substance.

For NaCl, it is electrolyte compound which dissociates to Na⁺ and Cl⁻.

<em>So, i for NaCl = 2.</em>

<em>∴ ΔTf for NaCl = iKf.m = (2)(Kf)(1.0 m) = 2 Kf.</em>

<em></em>

<em>So, the right choice is: 3) NaCl.</em>

<em></em>

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