Answer: -
0.1 ml of bleach should be added to each liter of test solution.
Explanation:-
Let the volume of bleach to be added is B ml.
Density of stock solution = 1.0 g/ml
Mass of stock solution = Volume of stock x density of stock
= B ml x 1.0 g/ml
= B g
Amount of NaOCl in this stock solution = 5% of B g
=
x B g
= 0.05 B g
Now each test solution must be added 5 mg/l NaOCl.
Thus each liter of test solution must have 5 mg.
Thus 0.05 B g = 5 mg
= 0.005 g
B = 
= 0.1
Thus 0.1 ml of bleach should be added to each liter of test solution.
Answer:
ΔH = 57.04 Kj/mole H₂O
Explanation:
60ml(0.300M Ba(OH)₂(aq) + 60ml(0.600M HCl(aq)
=> 0.06(0.3)mole Ba(OH)₂(aq) + 0.60(0.6)mole HCl(aq)
=> 0.018mole Ba(OH)₂(aq) + 0.036mole HCl(aq)
=> 100% conversion of reactants => 0.018mole BaCl₂(aq) + 0.036mole H₂O(l) + Heat
ΔH = mcΔT/moles H₂O <==> Heat Transfer / mole H₂O
=(120g)(4.0184j/g°C)(27.74°C - 23.65°C)/(0.036mole H₂O)
ΔH = 57,042 j/mole H₂O = 57.04 Kj/mole H₂O