Explanation:
21. The given molecule for cracking is tetradecane.
On cracking it forms one mole of decane (C10H22) and two moles of ethene gas.
The chemical equation is shown below:
22. The essential condition for the formation of an ester is the reaction of alcohol and acid in presence of concentrated sulfuric acid.
Thus among the given options, the first option is the correct one.
23. Isomers of butanol are shown below:
It is 2-butanol.
The position of -OH group changes to the second carbon.
Explanation believe the answer is A. Average.
Grams ethanol = 33 ml times .789 gms/ml = 26.037 gms
<span>Moles ethanol = 26.037 gms / 46 gms/mole = .57 moles </span>
<span>Moles water = 67 ml or 67 grams/18 gms/mole = 3.22 moles </span>
<span>total moles = .57 + 3.72 = 4.29 moles </span>
<span>Mole fraction ethanol = .57 moles ethanol / 4.29 moles total = 0.13</span>
<span>Moles fraction water = 3.72 moles water / 4.29 moles total = 0.87</span>
<span>Partial pressure of ethanol = mole fraction ethanol (.13) _ times VP ethanol 43.9 torr) = 5.707 torr </span>
<span>partial pressure water = mole fraction water .87) times VP water (l7.5 torr) = 15.23 torr </span>
<span>Total vapor pressure over solution = 5.71 torr + 15.23 torr = 20.94 torr</span>
