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sertanlavr [38]
4 years ago
5

Using the thermodynamic information in the ALEKS Data tab, calculate the standard reaction free energy of the following chemical

reaction:NOCL---> NO+CLUsing the thermodynamic information in the ALEKS&nRound your answer to zero decimal places
Chemistry
1 answer:
julia-pushkina [17]4 years ago
6 0

Answer:

43.0 kJ

Explanation:

The free energy (ΔG) measures the total energy that is presented in a thermodynamic system that is available to produce useful work, especially at thermal machines. In a reaction, the value of the variation of it indicates if the process is spontaneous or nonspontaneous because the free energy intends to decrease, so, if ΔG < 0, the reaction is spontaneous.

The standard value is measured at 25°C, 298 K, and the value of free energy varies with the temperature. It can be calculated by the standard-free energy of formation (G°f), and will be:

ΔG = ∑n*G°f products - ∑n*G°f reactants, where n is the coefficient of the substance in the balanced reaction.

By the balanced reaction given:

2NOCl(g) --> 2NO(g) + Cl2(g)

At ALEKS Data tab:

G°f, NOCl(g) = 66.1 kJ/mol

G°f, NO(g) = 87.6 kJ/mol

G°f, Cl2(g) = 0 kJ/mol

ΔG = 2*87.6 - 2*66.1

ΔG = 43.0 kJ

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zimovet [89]

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Mostly Para

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Now the nitration reaction is a reaction in which the nitric acid in presence of sulfuric acid, react with the benzene molecule, to introduce the nitro group into the molecule. The nitro group is a relative strong deactiviting group and is metha director, so, further reactions that occur will be in the metha position.

Now, in this case, the methyl group is a weak activating group in the molecule of benzene, and is always ortho and para director for the simple fact that this molecule (The methyl group) is a donor of electrons instead of atracting group of electrons. Therefore for these two reasons, when the nitration occurs,it will go to the ortho or para position.

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