Answer:
Explanation:
Homogeneous mixture is a mixture in which the components of the mixture are in the same proportion throughout any sample extracted from the mixture while an heterogeneous mixture is a mixture in which the components of the mixture differ in term of proportion when different samples of the mixture are extracted and compared.
For example, a sandy water will have some parts (usually the bottom) of the mixture with more sand than other parts of the mixture, hence, it (sandy water) is a heterogeneous mixture. While salty and ocean water has it's salt dissolved in the same proportion throughout the water in the mixture, hence salty and/or ocean water is a homogeneous mixture.
Sandy water can be separated by filtration (i.e using a filter paper to separate the sand from the water when the mixture is poured over a filter paper) while salty and ocean water can be separated by distillation (i.e boiling of the mixture so the water molecules can boil and move through a tube as gas or steam into another container where they are cooled and converted back to liquid or water while leaving the solid salt component of the mixture in the boiling tube).
0.040 mol / dm³. (2 sig. fig.)
<h3>Explanation</h3>
in this question acts as a weak base. As seen in the equation in the question, produces 
rather than 
when it dissolves in water. The concentration of will likely be more useful than that of for the calculations here.
Finding the value of ![[\text{OH}^{-}]](https://tex.z-dn.net/?f=%5B%5Ctext%7BOH%7D%5E%7B-%7D%5D)
from pH:
Assume that 
,
.
![[\text{OH}^{-}] =10^{-\text{pOH}} =10^{-2.80} = 1.59\;\text{mol}\cdot\text{dm}^{-3}](https://tex.z-dn.net/?f=%5B%5Ctext%7BOH%7D%5E%7B-%7D%5D%20%3D10%5E%7B-%5Ctext%7BpOH%7D%7D%20%3D10%5E%7B-2.80%7D%20%3D%201.59%5C%3B%5Ctext%7Bmol%7D%5Ccdot%5Ctext%7Bdm%7D%5E%7B-3%7D)
.
Solve for ![[(\text{CH}_3)_3\text{N}]_\text{initial}](https://tex.z-dn.net/?f=%5B%28%5Ctext%7BCH%7D_3%29_3%5Ctext%7BN%7D%5D_%5Ctext%7Binitial%7D)
:
![\dfrac{[\text{OH}^{-}]_\text{equilibrium}\cdot[(\text{CH}_3)_3\text{NH}^{+}]_\text{equilibrium}}{[(\text{CH}_3)_3\text{N}]_\text{equilibrium}} = \text{K}_b = 1.58\times 10^{-3}](https://tex.z-dn.net/?f=%5Cdfrac%7B%5B%5Ctext%7BOH%7D%5E%7B-%7D%5D_%5Ctext%7Bequilibrium%7D%5Ccdot%5B%28%5Ctext%7BCH%7D_3%29_3%5Ctext%7BNH%7D%5E%7B%2B%7D%5D_%5Ctext%7Bequilibrium%7D%7D%7B%5B%28%5Ctext%7BCH%7D_3%29_3%5Ctext%7BN%7D%5D_%5Ctext%7Bequilibrium%7D%7D%20%3D%20%5Ctext%7BK%7D_b%20%3D%201.58%5Ctimes%2010%5E%7B-3%7D)
Note that water isn't part of this expression.
The value of Kb is quite small. The change in is nearly negligible once it dissolves. In other words,
![[(\text{CH}_3)_3\text{N}]_\text{initial} = [(\text{CH}_3)_3\text{N}]_\text{final}](https://tex.z-dn.net/?f=%5B%28%5Ctext%7BCH%7D_3%29_3%5Ctext%7BN%7D%5D_%5Ctext%7Binitial%7D%20%3D%20%5B%28%5Ctext%7BCH%7D_3%29_3%5Ctext%7BN%7D%5D_%5Ctext%7Bfinal%7D)
.
Also, for each mole of produced, one mole of 
was also produced. The solution started with a small amount of either species. As a result,
![[(\text{CH}_3)_3\text{NH}^{+}] = [\text{OH}^{-}] = 10^{-2.80} = 1.58\times 10^{-3}\;\text{mol}\cdot\text{dm}^{-3}](https://tex.z-dn.net/?f=%5B%28%5Ctext%7BCH%7D_3%29_3%5Ctext%7BNH%7D%5E%7B%2B%7D%5D%20%3D%20%5B%5Ctext%7BOH%7D%5E%7B-%7D%5D%20%3D%2010%5E%7B-2.80%7D%20%3D%201.58%5Ctimes%2010%5E%7B-3%7D%5C%3B%5Ctext%7Bmol%7D%5Ccdot%5Ctext%7Bdm%7D%5E%7B-3%7D)
.
![\dfrac{[\text{OH}^{-}]_\text{equilibrium}\cdot[(\text{CH}_3)_3\text{NH}^{+}]_\text{equilibrium}}{[(\text{CH}_3)_3\text{N}]_\textbf{initial}} = \text{K}_b = 1.58\times 10^{-3}](https://tex.z-dn.net/?f=%5Cdfrac%7B%5B%5Ctext%7BOH%7D%5E%7B-%7D%5D_%5Ctext%7Bequilibrium%7D%5Ccdot%5B%28%5Ctext%7BCH%7D_3%29_3%5Ctext%7BNH%7D%5E%7B%2B%7D%5D_%5Ctext%7Bequilibrium%7D%7D%7B%5B%28%5Ctext%7BCH%7D_3%29_3%5Ctext%7BN%7D%5D_%5Ctextbf%7Binitial%7D%7D%20%3D%20%5Ctext%7BK%7D_b%20%3D%201.58%5Ctimes%2010%5E%7B-3%7D)
,
![[(\text{CH}_3)_3\text{N}]_\textbf{initial} =\dfrac{[\text{OH}^{-}]_\text{equilibrium}\cdot[(\text{CH}_3)_3\text{NH}^{+}]_\text{equilibrium}}{\text{K}_b}](https://tex.z-dn.net/?f=%5B%28%5Ctext%7BCH%7D_3%29_3%5Ctext%7BN%7D%5D_%5Ctextbf%7Binitial%7D%20%3D%5Cdfrac%7B%5B%5Ctext%7BOH%7D%5E%7B-%7D%5D_%5Ctext%7Bequilibrium%7D%5Ccdot%5B%28%5Ctext%7BCH%7D_3%29_3%5Ctext%7BNH%7D%5E%7B%2B%7D%5D_%5Ctext%7Bequilibrium%7D%7D%7B%5Ctext%7BK%7D_b%7D)
,
![[(\text{CH}_3)_3\text{N}]_\text{initial} =\dfrac{(1.58\times10^{-3})^{2}}{6.3\times10^{-5}} = 0.040\;\text{mol}\cdot\text{dm}^{-3}](https://tex.z-dn.net/?f=%5B%28%5Ctext%7BCH%7D_3%29_3%5Ctext%7BN%7D%5D_%5Ctext%7Binitial%7D%20%3D%5Cdfrac%7B%281.58%5Ctimes10%5E%7B-3%7D%29%5E%7B2%7D%7D%7B6.3%5Ctimes10%5E%7B-5%7D%7D%20%3D%200.040%5C%3B%5Ctext%7Bmol%7D%5Ccdot%5Ctext%7Bdm%7D%5E%7B-3%7D)
.
Periodic Trend:
The Atomic radius of atoms generally decreases from left to right across a period
Group Trend:
The atomic radius of atoms generally increases from top to bottom within a group. As atomic number increases down a group, there is a increase in the positive nuclear charge, however the co-occurring increase in the number of orbitals wins out, increasing the atomic radius down a group in the periodic table
Answer :
The Atom with the greatest atomic radius is chlorine. Fluorine can be ruled out because it is in the same period as oxygen and further to the right down the period. Chlorine has the largest atomic size because it is farthest down the group of any of the above elements listed.
