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3 years ago

Pressure of gas in kilopascals

Chemistry

1 answer:

Pavlova-9 [17]3 years ago

7 0

Use the formula (P1V1)/T1 = (P2V2)/T2
(12.8 * 100)/(-108 + 273) = (.855 * P2)/(22 + 273) Need to convert Celsius into Kelvins
1280/165 = (0.855 * P2)/295
7.755556 = 0.002898 * P2
P2 = 2676.18 kPa
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Using the equations

Anna [14]

Considering the Hess's Law, the enthalpy change for the reaction is 221.8 kJ/mol.

Hess's Law indicates that the enthalpy change in a chemical reaction will be the same whether it occurs in a single stage or in several stages. That is, the sum of the ∆H of each stage of the reaction will give us a value equal to the ∆H of the reaction when it occurs in a single stage.

In this case you want to calculate the enthalpy change of:

C₂H₄ (g) + 6 F₂ (g) → 2 CF₄ (g) + 4 HF (g)

which occurs in three stages.

You know the following reactions, with their corresponding enthalpies:

Equation 1: H₂ (g) + F₂ (g) → 2 HF (g) ∆H° = -79.2 kJ/mol

Equation 2: C (s) + 2 F₂ (g) → CF₄ (g) ∆H° = 141.3 kJ/mol

Equation 3: 2 C(s) + 2 H₂ (g) → C₂H₄ (g) ∆H° = -97.6 kJ/mol

Because of the way formation reactions are defined, any chemical reaction can be written as a combination of formation reactions, some going forward and some going back.

<h3 /><h3>FIRST STEP</h3>

First, to obtain the enthalpy of the desired chemical reaction you need one mole of C₂H₄ (g) on reactant side and it is present in first equation. Since this equation has one mole of C₂H₄ (g) on the product side, it is necessary to locate it on the reactant side (invert it).

When an equation is inverted, the sign of ΔH° also changes.

<h3>SECOND STEP</h3>

Now, you need 2 moles of CF₄ (g) on the product side. The second equation has 1 mole of CF₄ (g) on the product side, so it is necessary to multiply it by 2 to obtain 2 moles of CF₄ (g).

Since enthalpy is an extensive property, that is, it depends on the amount of matter present, since the equation is multiply by 2, the variation of enthalpy also.

<h3>THIRD STEP</h3>

Finally, you need 4 moles of HF (g) on the product side. The first equation has 2 moles of HF (g) on the product side, so it is necessary to multiply it by 2 to obtain 4 moles of the compound.

Since the equation is multiply by 2, the variation of enthalpy also is multiplied by 2.

<h3>SUMMARY</h3>

In summary, you know that three equations with their corresponding enthalpies are:

Equation 1: 2 H₂ (g) + 2 F₂ (g) → 4 HF (g) ∆H° = -158.4 kJ/mol

Equation 2: 2 C (s) + 4 F₂ (g) → 2 CF₄ (g) ∆H° = 282.6 kJ/mol

Equation 3: C₂H₄ (g) → 2 C(s) + 2 H₂ (g) ∆H° = 97.6 kJ/mol

Adding or canceling the reactants and products as appropriate, and adding the enthalpies algebraically, you obtain:

C₂H₄ (g) + 6 F₂ (g) → 2 CF₄ (g) + 4 HF (g) ΔH°= 221.8 kJ/mol

Finally, the enthalpy change for the reaction is 221.8 kJ/mol.

Learn more about molar enthalpy:

7 0

2 years ago

The vapor pressure of methanol is 143 mmhg. identify the best reason to explain why methanol spontaneously evaporates in open ai

goldfiish [28.3K]

Answer/Explanation:

Methanol has a molecular weight (32.04 g/mol), low-boiling point and because of its low boiling point, methanol readily evaporates at room temperature.

Under these specified non-standard conditions, the partial pressure of methanol is lower than its vapor pressure and this explains the reason for the spontaneous evaporation exhibited by methanol.

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3 years ago

1. Ethanol and 2,6-dimethylphenol both have hydroxyl groups that can be deprotonated by a base. Why does ethanol act as a solven

Volgvan

Anions are solvated in protic hydrogen-bonding solvents (such as ethanol). Consequently, nucleophiles are less reactive. Since soft nucleophiles are less strongly solvated than hard nucleophiles, these solvents boost the relative reactivity of soft anions.

<h3>Ethanol is either a nucleophile or a base.</h3>

The ethanol is a base Because carbocation is an extremely reactive species, a base or nucleophile as weak as ethanol can replace or remove it. SN1 and E1 would not be conceivable without the carbocation or a strong departing group.

<h3>How do solvents impact anionic nucleophile's reactivity?</h3>

In polar aprotic solvents, nucleophilic substitution reactions of anionic nucleophiles often proceed more quickly. The normal relative reactivity order in such solvents (like DMSO)is Anions are solvated in protic hydrogen-bonding solvents (such as ethanol). Consequently, nucleophiles are less reactive.

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