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o-na [289]
3 years ago
13

What is the freezing point of a solution of 465 g of sucrose c12h22o11 dissolved in 575 ml of water?

Chemistry
1 answer:
Amanda [17]3 years ago
6 0

Answer:

The freezing point of the solution is - 4.39 °C.

Explanation:

We can solve this problem using the relation:

<em>ΔTf = (Kf)(m),</em>

where, ΔTf is the depression in the freezing point.

Kf is the molal freezing point depression constant of water = -1.86 °C/m,

density of water = 1 g/mL.

<em>So, the mass of 575 mL is 575 g = 0.575 kg.</em>

m is the molality of the solution (m = moles of solute / kg of solvent = (465 g / 342.3 g/mol)/(0.575 kg) = 2.36 m.

<em>∴ ΔTf = (Kf)(m</em>) = (-1.86 °C/m)(2.36 m) = <em>- 4.39 °C.</em>

<em>∵ The freezing point if water is 0.0 °C and it is depressed by - 4.39 °C.</em>

<em>∴ The freezing point of the solution is - 4.39 °C.</em>

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Explanation:

∵ ∆G°rxn = ∆H°rxn - T∆S°rxn.

Where, ∆G°rxn is the standard free energy change of the reaction (J/mol).

∆H°rxn is the standard enthalpy change of the reaction (J/mol).

T is the temperature of the reaction (K).

∆S°rxn is the standard entorpy change of the reaction (J/mol.K).

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∵ ∆H°rxn = ∑∆H°products - ∑∆H°reactants

<em>∴ ∆H°rxn = (2 x ∆H°f NOCl) - (1 x ∆H°f Cl₂) - (2 x ∆H°f NO) </em>= (2 x 51.71 kJ/mol) - (1 x 0) - (2 x 90.29 kJ/mol) = - 77.16 kJ/mol.

  • Calculating ∆S°rxn:

∵  ∆S°rxn = ∑∆S°products - ∑∆S°reactants

<em>∴ ∆S°rxn = (2 x ∆S° NOCl) - (1 x ∆S° Cl₂) - (2 x ∆S° NO) </em>= (2 x 261.6 J/mol.K) - (1 x 223.0 J/mol.K) - (2 x 210.65 J/mol.K) =<em> - 121.1 J/mol.K. = - 0.1211 kJ/mol.K.</em>

<em></em>

  • Calculating ∆G°rxn:

∵ ∆G°rxn = ∆H°rxn - T∆S°rxn.

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