The Relative Formula Mass of NaH2PO4 is 120 g/mol
Therefore, the number of moles = 6.6/120
= 0.055 moles of NaH2PO4 which is also equal to the number of moles of H2PO4.
[H2PO4-] = Number of moles oof H2PO4-/Volume of the solution in L
= 0.055/ ( 355 ×10^-3)
= 0.155 M
Na2HPO4 undergoes complete dissociation as follows;
Na2HPO4 (aq)= 2Na+ (aq) + HPO4^2- (aq)
1 mole of Na2HPO4 = 142 g/mol
Therefore; number of moles = 8.0/142
= 0.0563 moles
[HPO4 ^-2] is given by no of moles HPO4^2- /volume of the solution in L
= 0.0563/(355×10^-3)
= 0.1586 M
Both H2PO4^2- and HPO4^2- are weak acids the undergoes partial dissociation
Ka of H2PO4- = 6.20 × 10^-8
[H+] =Ka*([H2PO4-]/[HPO4(2-)]
= (6.20 ×10^-8)×(0.155/0.1586)
= 6.059 ×10^-8 M
pH = - log[H+]
= - log (6.059×10^-8)
= 7.218
Number of moles =
so to calculate molar mass (Molecular weight of compound):
Molecular weight =
=
= 50 g / mole
Now we calculate molecular weight of each compound in choices:
a) C₂H₄O = 44
b) CO₂ = 44
c) CH₃Cl = 50.4 ALMOST 50 so this is the correct answer
d) C₂H₆ = 30
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Answer: I & III
Explanation: Solutes are the substances which are minimum in quantity and which is required to dissolve in the solvent (which is larger in quantity) in order to make a solution.
In the asked question, it is given that the water is the solvent and from the given solutes we have to pick which would make an aqueous solution with the highest concentration of solute possible.
Thus the most appropriate answers could be the Ammonia and hexanol which can make the highest possible concentration of solute as ammonia is the gas which is highly soluble in water and hexanol is an alcohol which has an affinity for water. Thus the correct option is I & III
