When ice melts, the physicals state changes from solid to liquid. The energy or the heat required (q) required to change a unit mass (m) of a substance from solid to liquid is known as the enthalpy or heat of fusion (ΔHf). The variables; q, m and ΔHf are related as:
q = m * ΔHf
the mass of ice m = 65 g
the heat of fusion of water at 0C = ΔHf = 334 J/g
Therefore: q = 65 g * 334 J/g = 21710 J
Now:
4.184 J = 1 cal
which implies that: 21710 J = 1 cal * 21710 J/4.184 J = 5188.8 cal
Hence the heat required is 5188.8 cal or 5.2 Kcal (approx)
Explanation:
The given data is as follows.
Current (I) = 3.50 amp, Mass deposited = 100.0 g
Molar mass of Cr = 52 g
It is known that 1 faraday of electricity will deposit 1 mole of chromium. As 1 faraday means 96500 C and 1 mole of Cr means 52 g.
Therefore, 100 g of Cr will be deposited by "z" grams of electricity.

z = 
= 185576.9 C
As we know that, Q = I × t
Hence, putting the given values into the above equation as follows.
Q = I × t
185576.9 C =
t = 53021.9 sec
Thus, we can conclude that 100 g of Cr will be deposited in 53021.9 sec.