Answer:
Amount of excess Carbon (ii) oxide left over = 23.75 g
Explanation:
Equation of the reaction: Fe₂O₃ + 3CO ----> 2Fe + 3CO₂
Molar mass of Fe₂O₃ = 160 g/mol;
Molar mass of Carbon (ii) oxide = 28 g/mol
From the equation of reaction, 1 mole of Fe₂O₃ reacts with 3 moles of carbon (ii) oxide; i.e. 160 g of iron (iii) oxide reacts with 84 g (3 * 28 g) of carbon (ii) oxide
450 g of Fe₂O₃ will react with 450 * 84/180) g of carbon (ii) oxide = 236..25 g of carbon (ii) oxide
Therefore the excess reactant is carbon (ii) oxide.
Amount of excess Carbon (ii) oxide left over = 260 - 236.25
Amount of excess Carbon (ii) oxide left over = 23.75 g
<h3><u>Full Question:</u></h3>
The following compound has been found effective in treating pain and inflammation (J. Med. Chem. 2007, 4222). Which sequence correctly ranks each carbonyl group in order of increasing reactivity toward nucleophilic addition?
A) 1 < 2 < 3
B) 2 < 3 < 1
C) 3 < 1 < 2
D) 1 < 3 < 2
<h3><u>Answer: </u></h3>
The rate of nucleophilic attack of carbonyl compounds is 2<3 <1.
Option B
<h3><u>Explanation. </u></h3>
Nucleophilic attack is explained as the attack of an electron rich radical to a carbonyl compound like aldehyde or a ketone. A nucleophile has a high electron density, so it searches for a electropositive atom where it can donate a portion of its electron density and become stable.
A carbonyl compound is a
hybridized carbon atom with a double bonded oxygen atom in it. The oxygen atom pulls a huge portion of electron density from carbon being very electropositive.
In a ketone, there are two factors that make it less likely to undergo a nucleophilic attack than aldehyde. Firstly, the steric hindrance of two carbon groups being attached with the carbonyl carbon makes it harder for the nucleophile to approach. Secondly, the electron push by the carbon groups attached makes the carbonyl carbon a bit less electropositive than the aldehyde one. So aldehydes are more reactive towards a nucleophilic addition reaction.
First one is true second one is False
Answer:
Thus, the order of the reaction is 2.
The rate constant of the graph which is :- 2.00 M⁻¹s⁻¹
Explanation:
The kinetics of a reaction can be known graphically by plotting the concentration vs time experimental data on a sheet of graph.
The concentration vs time graph of zero order reactions is linear with negative slope.
The concentration vs time graph for a first order reactions is a exponential curve. For first order kinetics the graph between the natural logarithm of the concentration vs time comes out to be a straight graph with negative slope.
The concentration vs time graph for a second order reaction is a hyberbolic curve. Also, for second order kinetics the graph between the reciprocal of the concentration vs time comes out to be a straight graph with positive slope.
Considering the question,
A plot of 1/[NOBr] vs time give a straight line with a slope of 2.00 M⁻¹s⁻¹.
<u>Thus, the order of the reaction is 2.</u>
<u>Also, slope is the rate constant of the graph which is :- 2.00 M⁻¹s⁻¹</u>