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Answer:
we will use the Clausius-Clapeyron equation to estimate the vapour pressures of the boiling ethanol at sea level pressure of 760mmHg:
ln (P2/P1) = -
)
where
P1 and P2 are the vapour pressures at temperatures T1 and T2
Δ vapH = the enthalpy of vaporization of the ETHANOL
R = the Universal Gas Constant
In this problem,
P 1 = 100 mmHg
; T 1 = 34.7 °C = 307.07 K
P 2 = 760mmHg
T 2 =T⁻²=?
Δ vap H = 38.6 kJ/mol
R = 0.008314 kJ⋅K -1 mol -1
ln ( 760/10)=(0.00325 - T⁻²) (38.6kJ⋅mol-1 /0.008314 )
0.0004368=(0.00325 - T⁻²)
T⁻²=0.002813
T² = 355.47K
Answer:- The formula tells us that one formula unit of this compound is composed of one calcium atom, two nitrogen atoms, and six oxygen atoms.
Explanations:- Subscripts tell us about the number of atoms of the element for which they are used. For example, here the subscript of Ca is one, it means there is one calcium atom in the given one formula unit.
When we have subscripts inside and outside the parenthesis then they are multiplied and the outside subscript is considered for all the atoms present inside the parenthesis.
Here, for the given chemical formula, the subscript of N is 1 and the subscript present outside is 2. So, 1 x 2 = 2 and for oxygen, 3 x 2 = 6
So, we have one calcium atom, two nitrogen atoms and six oxygen atoms for one formula unit of given compound.