HELP PLEASE!!!! Identify the position of each chemical family on the periodic table

1. Show that heat flows spontaneously from high temperature to low temperature in any isolated system (hint: use entropy change

Inga [223]

Answer:

1 ) Δs ( entropy change for hot block ) = - Q / th ( -ve shows heat lost to cold block )

Δs ( entropy change for cold block ) = Q / tc

∴ Total Δs = ΔSc + ΔSh

= Q/tc - Q/th

2) ΔSdecomposition = Δh / Temp = ( 181.6 * 10^3 / 773 ) = 234.928 J/k

Explanation:

1) To show that heat flows spontaneously from high temperature to low temperature

example :

Pick two(2) solid metal blocks with varying temperatures ( i.e. one solid block is hot and the other solid block is cold )

Place both blocks for time (t ) in an insulated system to reduce heat loss or gain to or from the environment

Check the temperature of both blocks after time ( t ) it will be observed that both blocks will have same temperature after time t ( first law of thermodynamics )

Δs ( entropy change for hot block ) = - Q / th ( -ve shows heat lost to cold block )

Δs ( entropy change for cold block ) = Q / tc

∴ Total Δs = ΔSc + ΔSh

= Q/tc - Q/th

2) Entropy change for Decomposition of mercuric oxide

2HgO (s) → 2Hg(l) + O₂ (g)

Δs = positive

there is transition from solid to liquid and the melting point of mercury ( the point at which reaction will take place ) = 500⁰C

hence ΔSdecomposition = S⁻ Hg - S⁻ HgO =

Δh of reaction = 181.6 KJ

Temp = 500 + 273 = 773 k

hence ΔSdecomposition = Δh / Temp = ( 181.6 * 10^3 / 773 ) = 234.928 J/k

8 0

3 years ago

Calculate the initial rate for the formation of C at 25 ∘C, if [A]=0.50M and [B]=0.075M.Express your answer to two significant f

N76 [4]

The question is incomplete, here is the complete question:

Calculate the initial rate for the formation of C at 25°C, if [A]=0.50 M and [B]=0.075 M. Express your answer to two significant figures and include the appropriate units.Consider the reaction

A + 2B ⇔ C

whose rate at 25°C was measured using three different sets of initial concentrations as listed in the following table:

The table is attached below as an image.

Answer: The initial rate for the formation of C at 25°C is $2.25\times 10^{-2}Ms^{-1}$

Explanation:

Rate law is defined as the expression which expresses the rate of the reaction in terms of molar concentration of the reactants with each term raised to the power their stoichiometric coefficient of that reactant in the balanced chemical equation.

For the given chemical equation:

$A+2B\rightleftharpoons C$

Rate law expression for the reaction:

$\text{Rate}=k[A]^a[B]^b$

where,

a = order with respect to A

b = order with respect to B

Expression for rate law for first trial:

$5.4\times 10^{-3}=k(0.30)^a(0.050)^b$ ....(1)

Expression for rate law for second trial:

$1.1\times 10^{-2}=k(0.30)^a(0.100)^b$ ....(2)

Expression for rate law for third trial:

$2.2\times 10^{-2}=k(0.50)^a(0.050)^b$ ....(3)

Dividing 2 by 1, we get:

$\frac{1.1\times 10^{-2}}{5.4\times 10^{-3}}=\frac{(0.30)^a(1.00)^b}{(0.30)^a(0.050)^b}\\\\2=2^b\\b=1$

Dividing 3 by 1, we get:

$\frac{2.2\times 10^{-2}}{5.4\times 10^{-3}}=\frac{(0.50)^a(0.050)^b}{(0.30)^a(0.050)^b}\\\\4.07=2^a\\a=2$

Thus, the rate law becomes:

$\text{Rate}=k[A]^2[B]^1$ ......(4)

Now, calculating the value of 'k' by using any expression.

Putting values in equation 1, we get:

$5.4\times 10^{-3}=k[0.30]^2[0.050]^1\\\\k=1.2M^{-2}s^{-1}$

Calculating the initial rate of formation of C by using equation 4, we get:

$k=1.2M^{-2}s^{-1}$

[A] = 0.50 M

[B] = 0.075 M

Putting values in equation 4, we get:

$\text{Rate}=1.2\times (0.50)^2\times (0.075)^1\\\\\text{Rate}=2.25\times 10^{-2}Ms^{-1}$

Hence, the initial rate for the formation of C at 25°C is $2.25\times 10^{-2}Ms^{-1}$

8 0

3 years ago

How many molecules are in 69 grams of Na?

12345 [234]

Molar mass Na = 23.0 g/mol

1 mol ---- 23.0 g
n mol ---- 69 g

n = 69 / 23.0

n = 3.0 moles

1 mole -------- 6.02x10²³ molecules
3.0 moles ---- ?

3.0 * 6.02x10²³ / 1

= 1.806x10²⁴ molecules

hope this helps!

7 0

2 years ago

In 1803, John Dalton proposed an atomic theory. Three critical pieces of this theory included the following:

ValentinkaMS [17]

D. Proton, electron, neutron.

6 0

3 years ago

A 10.0 g pat of butter raise the water level in a graduated cylinder by 11.6 mL. What is the density of the butter

Nina [5.8K]

- formula for density is mass divided by volume

therefore density of butter = 10.0g divided by 11.6ml = 0.8620689 g/cm³ ≈ 0.862 g/cm³ (3sf)

8 0

3 years ago