The rate constant of first order reaction at 32. 3 °C is 0.343 /s must be less the 0. 543 at 25°C.
First-order reactions are very commonplace. we have already encountered examples of first-order reactions: the hydrolysis of aspirin and the reaction of t-butyl bromide with water to present t-butanol. every other reaction that famous obvious first-order kinetics is the hydrolysis of the anticancer drug cisplatin.
The value of ok suggests the equilibrium ratio of products to reactants. In an equilibrium combination both reactants and merchandise co-exist. big ok > 1 merchandise are k = 1 neither reactants nor products are desired.
Rate constant K₁ = 0. 543 /s
T₁ = 25°C
Activation energy Eₐ = 75. 9 k j/mol.
T₂ = 32. 3 °C.
K₂ =?
formula;
log K₂/K₁= Eₐ /2.303 R [1/T₁ - 1/T₂]
putting the value in the equation
K₂ = 0.343 /s
Hence, The rate constant of first order reaction at 32. 3 °C is 0.343 /s
The specific rate steady is the proportionality consistent touching on the fee of the reaction to the concentrations of reactants. The fee law and the specific charge consistent for any chemical reaction should be determined experimentally. The cost of the charge steady is temperature established.
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Delta H of solution = -Lattice Energy + Hydration
<span>Delta H of solution=- (-730)+(-793) </span>
<span>Delta H of solution= -63kJ/mol </span>
<span>Now we find moles of LiI: </span>
<span>10gLiI/133.85g=.075moles </span>
<span>multiply moles to the delta H of solution to cross cancel moles. .75moles x -64kJ/mol =4.7</span>
Answer:
See explanation below
Explanation:
You are not providing the starting material, however, I manage to find a similar question to this, so I'm gonna use it as a basis to help you answer yours.
Now let's analyze what is happening in the reaction so we can predict the final product.
We have a ketone here, reacting at first with LDA. This is a very strong base that is commonly used in reactions with ketones and aldehydes to promove a condensation. To do this, as LDA is a strong base it will occur firts an acid base reaction, substracting the most acidic hydrogen in the molecule (Which in this case, is the Beta hydrogen of the carbonile). This will cause an enolate formation.
Then, this enolate will react with the CH3I and form a new product. The final result would be a ketone with a methyl group now attached. In the picture 2, you have the mechanism and final product.
Hope this helps
