Release less energy than it uses
Answer:
The mass of a system does not change during a chemical reaction
Explanation:
Correct Answers
Considering ideal gas:
PV= RTn
T= 25.2°C = 298.2 K
P1= 637 torr = 0.8382 atm
V1= 536 mL = 0.536 L
:. R=0.082 atm.L/K.mol
:. n= (P1V1)/(RT) = ((0.8382 atm) x (0.536 L))/
((0.082 atmL/Kmol) x (298.2K))
:. n= O.0184 mol
Then,
P2= 712 torr = 0.936842 atm
V2 = RTn/P2 = [(0.082atmL/
Kmol) x (298.2K) x (0.0184mol) ]/(0.936842atm)
:.V2 = 0.4796 L
OR
V2 = 479.6 ml
Answer:
The boiling point is 308.27 K (35.27°C)
Explanation:
The chemical reaction for the boiling of titanium tetrachloride is shown below:
Ti
⇒ Ti
ΔH°
(Ti
) = -804.2 kJ/mol
ΔH°
(Ti
) = -763.2 kJ/mol
Therefore,
ΔH°
= ΔH°
(Ti
) - ΔH°
(Ti
) = -763.2 - (-804.2) = 41 kJ/mol = 41000 J/mol
Similarly,
s°(Ti
) = 221.9 J/(mol*K)
s°(Ti
) = 354.9 J/(mol*K)
Therefore,
s° = s° (Ti
) - s°(Ti
) = 354.9 - 221.9 = 133 J/(mol*K)
Thus, T = ΔH°
/s° = [41000 J/mol]/[133 J/(mol*K)] = 308. 27 K or 35.27°C
Therefore, the boiling point of titanium tetrachloride is 308.27 K or 35.27°C.