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FinnZ [79.3K]
3 years ago
10

A 3.452 g sample containing an unknown amount of a Ce(IV) salt is dissolved in 250.0-mL of 1 M H2SO4. A 25.00 mL aliquot is anal

yzed by adding KI and titrating the I3– that forms with S2O32–. The end point was reached following the addition of 13.02 mL of 0.03428 M Na2S2O3. Calculate the weight percent of Ce4 in the sample.When should the indicator be added to this titration? (at the beginning or just before the end point?)
Chemistry
1 answer:
SOVA2 [1]3 years ago
5 0

Answer:

1,812 wt%

Explanation:

The reactions for this titration are:

2Ce⁴⁺ + 3I⁻ → 2Ce³⁺ + I₃⁻

I₃⁻ + 2S₂O₃⁻ → 3I⁻ + S₄O₆²⁻

The moles in the end point of S₂O₃⁻ are:

0,01302L×0,03428M Na₂S₂O₃ = 4,463x10⁻⁴ moles of S₂O₃⁻. As 2 moles of S₂O₃⁻ react with 1 mole of I₃⁻, the moles of I₃⁻ are:

4,463x10⁻⁴ moles of S₂O₃⁻×\frac{1molI_{3}^-}{2molS_{2}O_{3}^-} = 2,2315x10⁻⁴ moles of I₃⁻

As 2 moles of Ce⁴⁺ produce 1 mole of I₃⁻, the moles of Ce⁴⁺ are:

2,2315x10⁻⁴ moles of I₃⁻×\frac{2molCe^{4+}}{1molI_{3}^-} = 4,463x10⁻⁴ moles of Ce(IV). These moles are:

4,463x10⁻⁴ moles of Ce(IV)×\frac{140,116g}{1mol} = <em>0,0625 g of Ce(IV)</em>

As the sample has a 3,452g, the weight percent is:

0,0625g of Ce(IV) / 3,452g × 100 = <em>1,812 wt%</em>

I hope it helps!

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