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Angelina_Jolie [31]
4 years ago
15

For the following reaction in aqueous solution, identify all those species that will be spectator ions. Select all that apply.

Chemistry
1 answer:
FromTheMoon [43]4 years ago
7 0

The reaction is incorrect. The correct reaction is: Na₂SO₄ + Hg(NO₃)₂ → HgSO₄ + 2NaNO₃. The options are:

A. Hg₂SO₄

B. Na₂SO₄

C. Na⁺

D. NO₃⁻

E. SO₄⁻²

F. Hg₂(NO₃)₂

G. NaNO₃

H. Hg⁺²

Answer:

C, D, E, H

Explanation:

The ions are formed after dissociation of the compound in the solution. When they're negatively charged, they're called anions, when they're negatively charged, they're called cations. If the ion is presented on both sides of the reaction, it is called a spectator ion.

Thus, the reaction given:

Na₂SO₄ + Hg(NO₃)₂ → HgSO₄ + 2NaNO₃

So, let's do the dissociation.

Na₂SO₄ is formed by the ions Na⁺ and SO₄⁻²;

Hg(NO₃)₂ is formed by the ions Hg⁺² and NO₃⁻;

HgSO₄ is formed by the ions Hg⁺² and SO₄⁻²;

NaNO₃ is formed by the ions Na⁺ and NO₃⁻.

Thus, the spectator ions are Na⁺, SO₄⁻², Hg⁺², and NO₃⁻.

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Answer:

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Explanation:

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Each system of diene or triene has a given fixed value at which maximum absorption is expected to occur according to Woodward rules. This given fixed value is called the base or parent value. If the two double bonds are trans to each other, the diene is said to be transoid. If the two double bonds belong to different rings, the system is said to be heteroanular and the base value in each case is 215nm. If the double bonds are cis to each other (cisoid), or the two double bonds are in the same ring (homoanular), then the base value is 253nm.

Since λmax = base value + ∑ substituent contributions + ∑ other contributions, if the other contributions are not very significant, homoanular diene will have a greater λmax because of its larger base value compared to heteroanular diene. This correlates well with the fact that conjugated systems absorb at a longer wavelength.

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