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masha68 [24]
3 years ago
14

A buffer solution is 0.310 M in H2SO3 and 0.304 M in NaHSO3. If Ka1 forH2SO4 is 1.7e-2 , what is the pH of this buffer solution

Chemistry
1 answer:
natka813 [3]3 years ago
4 0

Answer:

pH of the buffer solution is 1.76

Explanation:

To find the pH of a buffer we can use Henderson-Hasselbalch equation:

pH = pKa + log [A⁻] / [HA]

<em>Where pKa is -log Ka= 1.77 And [A⁻] is molar concentration of conjugate base, NaHSO₃ and [HA] molar concentration of weak acid, H₂SO₃</em>

<em />

Replacing values of the problem:

pH = 1.77 + log [0.304M] / [0.310M]

pH = 1.76

<h3>pH of the buffer solution is 1.76</h3>
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BabaBlast [244]
V  ( NaOH ) = mL ?

M ( NaOH ) = 0.100 M

V ( HCl ) = 9.00 mL / 1000 => 0.009 L

M ( HCl ) = 0.0500 M

number of moles HCl:

n = M x V

n = 0.009 x 0.0500 => 0.00045 moles HCl

mole ratio:

<span>HCl + NaOH = NaCl + H2O
</span>
 1 mole HCl ---------------- 1 mole NaOH
 0.00045 moles HCl ----- ??

0.00045 x 1 / 1 => 0.00045 moles of NaOH

M = n / V

0.100 = 0.00045 / V

V = 0.00045 / 0.100

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6 0
3 years ago
Question 9
Evgesh-ka [11]

Answer:

0.382 atm

Explanation:

In order to find the pressure, you need to know the moles of carbon dioxide (CO₂) gas. This can be found by multiplying the mass (g) by the molar mass (g/mol) of CO₂. It is important to arrange the conversion in a way that allows for the cancellation of units.

Molar Mass (CO₂): 12.011 g/mol + 2(15.998 g/mol)

Molar Mass (CO₂): 44.007 g/mol

15 grams CO₂               1 mole
----------------------  x  ------------------------  =  0.341 moles CO₂
                                44.007 grams

To find the pressure, you need to use the Ideal Gas Law equation.

PV = nRT

In this equation,

-----> P = pressure (atm)

-----> V = volume (L)

-----> n = moles

-----> R = Ideal Gas Constant (0.08206 atm*L/mol*K)

-----> T = temperature (K)

After you convert Celsius to Kelvin, you can plug the given and calculated values into the equation and simplify to find the pressure.

P = ? atm                              R = 0.08206 atm*L/mol*K

V = 20 L                               T = 0 °C + 273.15 = 273.15 K

n = 0.341 moles

PV = nRT

P(20 L) = (0.341 moles)(0.08206 atm*L/mol*K)(273.15 K)

P(20 L) = 7.64016

P = 0.382 atm

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Which of the following metals (M) will form an ionic compound with nitrogen with the general formula M3N2?
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A 50.0 mL sample of a 1.00 M solution of CuSO4 is mixed with 50.0 mL of 2.00 M KOH in a calorimeter. The temperature of both sol
Scorpion4ik [409]

Answer:

see explanation

Explanation:

Step 1: Data given

Volume of 1M CusO4 = 50.0 mL = 0.05 L

Volume of 2M KOH = 50.0 mL = 0.05 L

Temperature before mixing= 17.8 °C

Temperature after mixing = 32.4 °C

The heat capacity of the calorimeter is 12.1 J/K

Step 2: The balanced equation

CuSO4(aq)+ 2KOH(aq) →Cu(OH)2(s) + K2SO4(aq)

Step 3: Calculate mass of the solution

Suppose the density of the solution is 1 g/mL

Total volume = 100 mL

Mass of the solution = density * volume

Mass of the solution = 1g/mL * 100 mL = 100 grams

Step 4:

Q = m*c*ΔT

with m = the mass of the solution = 100 grams

with c= the heat capacity of the solution = 4.184 J/g°C

with ΔT = 32.4 - 17. 8 = 14.6 °C

Q = 6108.64 J

Step 5: Calculate the energy of the calorimeter

Q = c*ΔT

Q = 12.1 J/K * 14.6

Q = 176.66 J

Step 6: Calculate total heat

Qtotal = 6108.64 + 176.66 = 6285.3 J = 6.29 kJ (negative because it's exothermic)

Step 7: Calculate moles

Moles CuSO4 = 0.05 L * 1M = 0.05 moles

Moles KOH = 0.05 L * 2M = 0.10 moles

ΔH = -6.29 kJ / 0.05 moles = -125.8 kJ/mol

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