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VladimirAG [237]
3 years ago
7

Density measurements were conducted on a 22.5oC sample of water which had a theoretical density of 0.997655 g/ml. A volume of 10

.00 ml of the water had a mass of 9.98 g. A volume of 15.00 ml of the water had a mass of 15.61 g. A volume of 25.00 ml of the water had a mass of 25.65 g. (1) Show the calculation of the density of each volume. (2) Show the calculation of the average density. (3) Show the calculation of the percent error based on the theoretical density of 0.997655 g/ml.
Chemistry
1 answer:
Sophie [7]3 years ago
7 0

Let's divide the three experiments: The experiment with 10.00 mL of water is A), the experiment with 15.00 mL is B), and the experiment with 25.00 mL is C).

  • (1) Now let's calculate the experimental density of each experiment. Density (ρ) is equal to the mass divided by the volume, thus:

p_{A} =9.98g/10.00mL=0.998g/mL\\p_{B} =15.61g/15.00mL=1.041g/mL\\p_{C} =25.65g/25.00mL=1.026g/mL

  • (2)To calculate the average density, we add each density and divide the result by the number of experiments (in this case 3):

p_{average}=\frac{p_{1}+p_{2}+p_{3}}{3}   \\p_{average}=\frac{(0.998+1.041+1.026)g/mL}{3}\\p_{average}=1.022g/mL

  • (3) The percent error is calculated by dividing the absolute value of the substraction of the theorethical and experimental values, by the theoretical value, times 100:

%error=\frac{|p_{average}-p_{theoretical}|}{p_{theoretical}} *100

%error=\frac{|1.022g/mL-0.997655g/mL|}{0.997655g/mL}*100

%error=2.44 %

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(a) The weight percent HNO3 is 63%.

(b) Density of HNO3 = 111.2 lb/ft3

(c) Molarity = 13792 mol HNO3/m3

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(a) Weight percent HNO3

To calculate a weight percent of a component of a solution we can express:

wt = \frac{mass \, of \, solute}{mass \, of \, solution}=\frac{mass\,HNO_3}{mass \, HNO_3+mass \, H_2O}\\  \\wt=\frac{1.704}{1.704+1} =\frac{1.704}{2.704}= 0.63

(b) Density of HNO3, in lb/ft3

In this calculation, we use the specific gravity of the solution (1.382). We can start with the volume balance:

V_s=V_{HNO3}+V_w\\\\\frac{M_s}{\rho_s}=\frac{M_{HNO3}}{\rho_{HNO3}}+\frac{M_w}{\rho_w}\\\\\frac{M_{HNO3}}{\rho_{HNO3}} = \frac{M_s}{\rho_s}-\frac{M_w}{\rho_w}\\\\\rho_{HNO3}=\frac{M_{HNO3}}{\frac{M_s}{\rho_s}-\frac{M_w}{\rho_w}} \\\\ \rho_{HNO3}=\frac{1.704}{\frac{2.704}{1.382*\rho_w}+\frac{1}{\rho_w}} \\\\ \rho_{HNO3}=\frac{1.704}{2.956/ \rho_w}= 0.576*\rho_w[tex]V_s=V_{HNO3}+V_w\\\\\frac{M_s}{\rho_s}=\frac{M_{HNO3}}{\rho_{HNO3}}+\frac{M_w}{\rho_w}\\\\\frac{M_{HNO3}}{\rho_{HNO3}} = \frac{M_s}{\rho_s}-\frac{M_w}{\rho_w}\\\\\rho_{HNO3}=\frac{M_{HNO3}}{\frac{M_s}{\rho_s}-\frac{M_w}{\rho_w}} \\\\ \rho_{HNO3}=\frac{1.704}{\frac{2.704}{1.382*\rho_w}-\frac{1}{\rho_w}} \\\\ \rho_{HNO3}=\frac{1.704}{0.956/\rho_w}= 1.782*\rho_w

The density of HNO3 is 1.782 times the density of water (Sp Gr of 1.782). If the density of water is 62.4 lbs/ft3,

\rho_{HNO3}= 1.782*\rho_w=1.782*62.4 \, lbs/ft3=111.2\, lbs/ft3

(c) HNO3 molarity (mol HNO3/m3)

If we use the molar mass of HNO3: 63.012 g/mol, we can say that in 1,704 kg (or 1704 g) of HNO3 there are  1704/63.012=27.04 mol HNO3.

When there are 1.704 kg of NHO3 in solution, the total mass of the solution is (1.704+1)=2.704 kg.

If the specific gravity of the solution is 1.382 and the density of water at 20 degC is 998 kg/m3, the volume of the solution is

Vol=\frac{M_{sol}}{\rho_{sol}}=\frac{2.704\, kg}{1.382*998 \, kg/m3} = 0.00196m3

We can now calculate the molarity as

Molarity HNO_3=\frac{MolHNO3}{Vol}=\frac{27.04mol}{0.00196m3}  =13792 \frac{molHNO3}{m3}

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