First, let's compute the number of moles in the system assuming ideal gas behavior.
PV = nRT
(663 mmHg)(1atm/760 mmHg)(60 L) = n(0.0821 L-atm/mol-K)(20+273 K)
Solving for n,
n = 2.176 moles
At standard conditions, the standard molar volume is 22.4 L/mol. Thus,
Standard volume = 22.4 L/mol * 2.176 mol =<em> 48.74 L</em>
Yes it is polluting the river with everything the manufaturing plant gives off such as the chemicals released in the air
