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3 years ago

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Nitric oxide reacts with chlorine to form nocl. the data refer to 298 k. 2no(g) + cl2(g) → 2nocl(g) substance: no(g) cl2(g) nocl

(g) ∆h°f (kj/mol): 90.29 0 51.71 ∆g°f (kj/mol): 86.60 0 66.07 s°(j/k·mol): 210.65 223.0 261.6 what is the value of ∆g° fo this reaction at 550 k?

1 answer:

tigry1 [53]3 years ago

4 0

Answer:

- 10.555 kJ/mol.

Explanation:

∵ ∆G°rxn = ∆H°rxn - T∆S°rxn.

Where, ∆G°rxn is the standard free energy change of the reaction (J/mol).

∆H°rxn is the standard enthalpy change of the reaction (J/mol).

T is the temperature of the reaction (K).

∆S°rxn is the standard entorpy change of the reaction (J/mol.K).

Calculating ∆H°rxn:

∵ ∆H°rxn = ∑∆H°products - ∑∆H°reactants

<em>∴ ∆H°rxn = (2 x ∆H°f NOCl) - (1 x ∆H°f Cl₂) - (2 x ∆H°f NO) </em>= (2 x 51.71 kJ/mol) - (1 x 0) - (2 x 90.29 kJ/mol) = - 77.16 kJ/mol.

Calculating ∆S°rxn:

∵ ∆S°rxn = ∑∆S°products - ∑∆S°reactants

<em>∴ ∆S°rxn = (2 x ∆S° NOCl) - (1 x ∆S° Cl₂) - (2 x ∆S° NO) </em>= (2 x 261.6 J/mol.K) - (1 x 223.0 J/mol.K) - (2 x 210.65 J/mol.K) =<em> - 121.1 J/mol.K. = - 0.1211 kJ/mol.K.</em>

<em></em>

Calculating ∆G°rxn:

∵ ∆G°rxn = ∆H°rxn - T∆S°rxn.

<em>∴ ∆G°rxn = ∆H°rxn - T∆S°rxn </em>= (- 77.16 kJ/mol) - (550 K)(- 0.1211 kJ/mol.K) = <em>- 10.555 kJ/mol.</em>

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Give the name and formula of the compound formed from the following elements: (a) sodium and nitrogen; (b) oxygen and strontium;

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<u>Answer:</u>

<u>For a:</u> The chemical name and chemical formula formed is sodium nitride and $Na_3N$

<u>For b:</u> The chemical name and chemical formula formed is strontium oxide and $SrO$

<u>For c:</u> The chemical name and chemical formula formed is aluminium chloride and $AlCl_3$

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For formation of a neutral ionic compound, the charges on cation and anion must be balanced. The cation is formed by loss of electrons by metals and anions are formed by gain of electrons by non metals.

The nomenclature of ionic compounds is given by:

1. Positive is written first.

2. The negative ion is written next and a suffix is added at the end of the negative ion. The suffix written is '-ide'.

<u>For a:</u> Sodium and nitrogen:

Sodium is the 11th element of periodic table having electronic configuration of $[Ne]3s^1$

To form $Na^{+}$ ion, this element will loose 1 electron.

Nitrogen is the 7th element of periodic table having electronic configuration of $[He]2s^22p^3$ .

To form $N^{3-}$ ion, this element will gain 3 electrons.

By criss-cross method, the oxidation state of the ions gets exchanged and they form the subscripts of the other ions. This results in the formation of a neutral compound.

So, the chemical formula for sodium nitride is $Na_3N$

<u>For b:</u> Oxygen and strontium

Strontium is the 38th element of periodic table having electronic configuration of $[Kr]5s^2$ .

To form $Sr^{2+}$ ion, this element will loose 2 electrons.

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To form $O^{2-}$ ion, this element will gain 2 electrons.

By criss-cross method, the oxidation state of the ions gets exchanged and they form the subscripts of the other ions. This results in the formation of a neutral compound.

So, the chemical formula for strontium oxide is $SrO$

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Aluminium is the 13th element of periodic table having electronic configuration of $[Ne]3s^23p^1$

To form $Al^{3+}$ ion, this element will loose 3 electrons.

Chlorine is the 17th element of the periodic table having electronic configuration of $[Ne]3s^23p^5$

To form $Cl^{-}$ ion, this element will gain 1 electron.

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1 year ago

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