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jasenka [17]
3 years ago
14

Hich one of the following statements about orbital hybridization is incorrect?

Chemistry
1 answer:
photoshop1234 [79]3 years ago
4 0

Answer : The incorrect statement is, (C) The nitrogen atom in NH₃ is sp² hybridized.

Explanation :

Formula used  :

\text{Number of electron pair}=\frac{1}{2}[V+N-C+A]

where,

V = number of valence electrons present in central atom

N = number of monovalent atoms bonded to central atom

C = charge of cation

A = charge of anion

Now we have to determine the hybridization of the following molecules.

(a) The given molecule is, CH_4

\text{Number of electrons}=\frac{1}{2}\times [4+4]=4

The number of electron pair are 4 that means the hybridization will be sp^3 and the electronic geometry of the molecule will be tetrahedral.

(b) The given molecule is, CO_2

\text{Number of electrons}=\frac{1}{2}\times [4]=2

The number of electron pair are 2 that means the hybridization will be sp and the electronic geometry of the molecule will be linear.

(c) The given molecule is, NH_3

\text{Number of electrons}=\frac{1}{2}\times [5+3]=4

The number of electron pair are 4 that means the hybridization will be sp^3 and the electronic geometry of the molecule will be tetrahedral.

But as there are 3 atoms around the central nitrogen atom, the fourth position will be occupied by lone pair of electrons. The repulsion between lone and bond pair of electrons is more and hence the molecular geometry will be trigonal pyramidal.

(d) sp² hybrid orbitals are coplanar, and at 120° to each other.

The sp² hybrid orbitals has trigonal planar geometry and are in the same plane that means coplanar. Thus, the bond angle is 120° to each other.

(e) sp hybrid orbitals lie at 180° to each other.

The sp hybrid orbitals has linear geometry. Thus, the bond angle is 180° to each other.

Hence, the incorrect statement is, (C) The nitrogen atom in NH₃ is sp² hybridized.

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4 years ago
Hclo is a weak acid (ka=4.0x10^-8) and so the salt naclo acts as a weak base. what is the ph of a solution that is 0.037 m in na
ankoles [38]

<u>Given:</u>

Concentration of NaClO = 0.037 M

ka (HClO) = 4.0*10⁻⁸

<u>To determine:</u>

The pH of the NaClO solution

<u>Explanation:</u>

The hydrolysis of the weak base can be represented by the ICE table shown below-

                ClO-      +     H2O    ↔    HClO    +       OH-

Initial        0.037M                              0                    0

Change         -x                                 +x                  +x

Equilibrium  (0.037-x)                        x                     x

kb  = kw/ka =  [HClO][OH-]/[ClO-]

10⁻¹⁴/4*10⁻⁸ = x²/(0.037-x)

x = [OH-] = 9.62*10⁻⁵

p[OH-] = -log[OH-] = -log [9.62*10⁻⁵] = 4.02

pH = 14-p[OH-] = 14 - 4.02 = 9.98

Ans: pH of the solution is 9.98


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1. In this experiment, what property of NaCl is used to separate it from the other two components? Is this a chemical or physica
irinina [24]

Answer 1) In the mixture of sand, NaCl and CaCO_{3} first separation was done by dissolving the mixture in water. In the first step the NaCl will get dissolved whereas, CaCO_{3} will be undissolved and sand will settle at the bottom. Here, the physical property of solubility of NaCl in water is taken into consideration. The collected water is then filtered off and evaporated to get the NaCl back from the mixture with some loss. No chemical change occurs in case of NaCl extraction from water.


Answer 2) When CaCO_{3} was to be removed from the undissolved part. The chemical property of CaCO_{3} was used. Where it gets dissolved in acidic medium. And this way we can extract CaCO_{3} and remove sand from it. We change the chemical composition of CaCO_{3} by adding HCl to the mixture and dissolve CaCO_{3} to form CaCl_{2} which gets dissolved into the solution of HCl. Here, first decantation occurs and then extraction is done. Second, extraction is done using potassium carbonate in it which separates CaCl_{2} from sand.


Answer 3) Here, Unknown mixture of salt and sand weighed =7.52 g (before washing);


Unknown mixture of salt and sand weighed =3.45 g (after washing);


To calculate the amount of salt in it, we can simply subtract the values of before and after washing change in weights.


The property of NaCl being soluble in water it will go away with washing leaving behind the sand only, after washing.


So, Weight of salt was = 7.52g - 3.45 g = 4.07g


To find the percentage of sand that was mixed with salt =

(3.45 g sand / 7.52g of mixture) X 100 = 45.9% sand was mixed with salt.


To verify whether the correct percentage of salt and sand was calculated we can recheck the value for salt as well.

(4.07 g of salt / 7.52g of mixture) X 100 = 54.1% salt


On adding we get, 45.9% + 54.1% = 100%.


Which confirms that the calculations are correct.

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