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Papessa [141]
3 years ago
14

Bath salts are typically composed of the ingredients listed below. Identify each item as being acidic, basic, or neutral when di

ssolved in water. If a particular ingredient does make an acidic or basic solution, describe how this occurs. Use the results of your in-lab observations, as well as your textbook and the provided Supplemental Information on pages 65-66, to support your conclusions. NaCI Na2SO4 NaHCO K3PO4 sodium citrate CaCl2 2. In Experiment SOL, you investigated the solubility of oxalic acid. Sodium oxalate, Na:C204, is the sodium salt of this acid. Categorize it as acidic, basic, or neutral i water. Does the salt dissolve, dissociate, or both in aqueous solutions? What about oxalic acid; does it dissolve, dissociate, or both in water? Explain.
Chemistry
1 answer:
Gwar [14]3 years ago
4 0

Answer:

NaCl neutral

Na₂SO₄ basic

NaHCO₃ basic

K₃PO₄ basic

Na₃C₆H₅O₇ basic

CaCl₂ neutral

Sodium oxalate (Na₂C₂O₄) dissolves and dissociates in water.

Oxalic acid (C₂H₂O₄) dissolves and dissociates in water

Explanation:

<em>Identify each item as being acidic, basic, or neutral when dissolved in water. If a particular ingredient does make an acidic or basic solution, describe how this occurs.</em>

<em />

NaCl

When NaCl is dissolved in water the resulting solution is neutral.

Na₂SO₄

When Na₂SO₄ is dissolved in water the resulting solution is basic due to the basic hydrolysis of the SO₄²⁻ ion.

SO₄²⁻(aq) + H₂O(l) ⇄ HSO₄⁻(aq) + OH⁻(aq)

NaHCO₃

When NaHCO₃ is dissolved in water the resulting solution is basic due to the basic hydrolysis of the HCO₃⁻ ion.

HCO₃⁻(aq) + H₂O(l) ⇄ H₂CO₃(aq) + OH⁻(aq)

K₃PO₄

When K₃PO₄ is dissolved in water the resulting solution is basic due to the basic hydrolysis of the PO₄³⁻ ion.

PO₄³⁻(aq) + H₂O(l) ⇄ HPO₄²⁻(aq) + OH⁻(aq)

Na₃C₆H₅O₇ (sodium citrate)

When Na₃C₆H₅O₇ is dissolved in water the resulting solution is basic due to the basic hydrolysis of the C₆H₅O₇³⁻ ion.

C₆H₅O₇³⁻(aq) + H₂O(l) ⇄ C₆H₆O₇²⁻(aq) + OH⁻(aq)

CaCl₂

When CaCl₂ is dissolved in water the resulting solution is neutral.

Sodium oxalate (Na₂C₂O₄) dissolves and dissociates in water according to the following equation:

Na₂C₂O₄(aq) ⇄ 2 Na⁺(aq) + C₂O₄²⁻(aq)

Oxalic acid (C₂H₂O₄) dissolves and dissociates in water according to the following equation:

C₂H₂O₄(aq) ⇄ C₂HO₄⁻(aq) + H⁺(aq)

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Answer:

a). P = 688 atm

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Explanation:

a). Fugacity 'f' can be calculated from the following equations :

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Now, the virial equation is :

$PV=R(1+6.4\times 10^{-4} P)$  ........(1)

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∴ $ZRT=RT(1+6.4\times 10^{-4} P)$

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So from the fugacity equation ,

$\ln \frac{f}{P}=\int^P_0\left(\frac{1+6.4\times 10^{-4}P-1}{P}\right) dP$

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b). Given f = 2P

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   $2=E^{6.4 \times 10^{-4}P}$

  $\ln 2 = 6.4 \times 10^{-4}P$

  ∴  P = 1083.04 atm

c). dG = Vdp -S dt  at constant temperature, dT = 0

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$\int^{G_2}_{G_1}dG =\int^{P_2}_{P_1}V dp $

            $=\int^{P_2}_{P_1}\frac{RT}{P}\left(1+6.4 \times 10^{-4}P\right) dP$

           $=\int^{P_2}_{P_1}RT\frac{dp}{P}+\int^{P_2}_{P_1}RT6.4 \times 10^{-4} dP$

$\Delta G=R[\ln\frac{P_2}{P_1}+6.4 \times 10^{-4}(P_2-P_1)]$

$\Delta G=8.314\times 298[\ln\frac{500}{1}+6.4 \times 10^{-4}(500-1)]$

Δ G = 16.188 J/mol  

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