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svlad2 [7]
3 years ago
15

Consider two concentric spheres whose radii differ by t = 1 nm, the "thickness" of the interface. At what radius (in nm) of sphe

re does the volume of a shell equal that of the interior sphere? Assume the shell thickness to be t = 1 nm.
Chemistry
1 answer:
Gala2k [10]3 years ago
8 0

Answer:

Radius of the interior sphere = 3.847 nm

Explanation:

The volume of the shell (Vs) is equal to the difference of the volume of the outer sphere (Vo) and the volume of the inner sphere (Vi). Then:

V_s=V_o-V_i=V_i\\V_o=2*V_i\\

If we express the radius of the outer sphere (ro) in function of the radius of the inner sphere (ri), we have (e being the shell thickness):

r_o=r_i+e

The first equation becomes

\frac{4 \pi}{3}*r_o^{3}  = 2 * \frac{4 \pi}{3}*r_i^{3}  \\\\\frac{4 \pi}{3}*(r_i+e)^{3}  = 2 * \frac{4 \pi}{3}*r_i^{3}  \\\\(r_i+e)^{3}  = 2 *r_i^{3}  \\\\(r_i^{3}+3r_i^{2}e+3r_ie^{2}+e^{3})=2r_i^{3}\\\\-r_i^{3}+3r_i^{2}e+3r_ie^{2}+e^{3}=0\\\\-r_i^{3}+3r_i^{2}+3r_i+1=0

To find ri that satisfies this equation we have to find the roots of the polynomial.

Numerically, it could be calculated that ri=3.847 nm satisfies the equation.

So if the radius of the interior sphere is 3.847 nm, the volume of the interior sphere is equal to the volume of the shell of 1nm.

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Answer:  

1) Endothermic.  

2) Q_{rxn}=4435.04J  

3) \Delta _rH=15.8kJ/mol

Explanation:  

Hello there!  

1) In this case, for these calorimetry problems, we can realize that since the temperature decreases the reaction is endothermic because it is absorbing heat from the solution, that is why the temperature goes from 22.00 °C to 16.0°C.  

2) Now, for the total heat released by the reaction, we first need to assume that all of it is released by the solution since it is possible to assume that the calorimeter is perfectly isolated. In such a way, it is also valid to assume that the specific heat of the solution is 4.184 J/(g°C) as it is mostly water, therefore, the heat released by the reaction is:

Q_{rxn}=-(15.0g+250.0g)*4.184\frac{J}{g\°C}(16.0-20.0)\°C\\\\ Q_{rxn}=4435.04J    

3) Finally, since the enthalpy of reaction is calculated by dividing the heat released by the reaction over the moles of the solute, in this case NH4Cl, we proceed as follows:

\Delta _rH=\frac{ Q_{rxn}}{n}\\\\\Delta _rH= \frac{ 4435.04J}{15.0g*\frac{1mol}{53.49g} } *\frac{1kJ}{1000J} \\\\\Delta _rH=15.8kJ/mol

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3 years ago
A sample of P2Cl5 contains 179 g of phosphorous, how many grams of chlorine are present? Please show step by step thx!
natima [27]

Answer:

About 512 g.

Explanation:

We are given a sample of P₂Cl₅ that contains 179 grams of phosphorus, and we want to determine the grams of chlroine that is present.

Thus, we can convert from grams of phosphorus to moles of phosphorus, moles of phosphorus to moles of chlorine, and moles of chlorine to grams of chlorine.

From the formula, there are two moles of P for every five moles of Cl. The molecular weights of P and Cl are 30.97 g/mol and 35.45 g/mol, respectively. Hence:

\displaystyle 179\text{ g P} \cdot \frac{1\text{ mol P}}{30.97\text{ g P}} \cdot \frac{5\text{ mol Cl}}{2\text{ mol P}} \cdot \frac{35.45\text{ g Cl}}{1\text{ mol Cl}} = 512\text{ g Cl}

In conclusion, there is about 512 grams of chlorine present in the sample.

Alternatively, we can mass percentages. The mass percent of phosphorus in P₂Cl₅ is:


\displaystyle \% \text{P} = \frac{2(30.97)}{5(35.45) + 2(30.97)} = 25.90\%

Because there are 179 grams of phosphorus, the total amount of sample present is:


\displaystyle \begin{aligned} 25.90\% \cdot  m_T  & = 179\text{ g P} \\ \\ m_T & = 691.1 \text{ g}\end{aligned}

Therefore, the amount of chlorine present is 691.1 g - 179 g, or about 512 g, in agreement with our above answer.

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