For the given molecule, we are asked to give-
- The electron configuration of an isolated B atom
- The electron configuration of an isolated F atom
- Hybrid orbitals should be constructed on the B atom to make the B–F bonds in Boron tri flouride
- valence orbitals, if any, remain unhybridized on the B atom.
- The electron configuration of an isolated B atom:
as atomic number of B is 5
electronic configuration will be [He] 2s² 2p¹
- The electron configuration of an isolated F atom:
as atomic number of F is 9
electronic configuration will be [He] 2s² 2p5
- Hybrid orbitals should be constructed on the B atom to make the B–F bonds in Boron tri flouride will be sp2.
as the one s and two of p orbital from the valance shell will hybridised to make 3 hybrid orbital of B resulting in 3 B-F bonds.
- valence orbitals, if any, remain unhybridized on the B atom will be 1
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Explanation:
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Explanation:
C) What is the multiplicity of Proton-alpha's signal in this scenario when there are 2 identical protons "next door"?
Based on n+1 rule. Here n=2 (identical beta protons).
2+1=3
So the multiplicity of alpha proton is triplet, .
D) For molecules containing only single bonds (we'll discuss the influence of double bonds in a future lecture), what is the adjective that describes the position of protons that split a "next door neighbor's" signal?
The meaning of the adjective is this: the multiplicity of beta protons is singlet only (no spliting) in absence of alpha proton . But beta protons splits as doublet (n=1) in the presence of alpha proton,
E) How many bonds connect these "splitting next door neighbors"?
There are 3 bonds in between alpha and beta protons in a molecule.
F) What is the multiplicity of the Proton-betas' signal?
Following the n+1 rule, here n=1 (1 alpha proton) so 1+1=2. Hence it is a doublet.